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Fostering research, careers, and community in materials science

Gabrielle Wood, a junior at Howard University majoring in chemical engineering, is on a mission to improve the sustainability and life cycles of natural resources and materials. Her work in the Materials Initiative for Comprehensive Research Opportunity (MICRO) program has given her hands-on experience with many different aspects of research, including MATLAB programming, experimental design, data analysis, figure-making, and scientific writing.

Wood is also one of 10 undergraduates from 10 universities around the United States to participate in the first MICRO Summit earlier this year. The internship program, developed by the MIT Department of Materials Science and Engineering (DMSE), first launched in fall 2021. Now in its third year, the program continues to grow, providing even more opportunities for non-MIT undergraduate students — including the MICRO Summit and the program’s expansion to include Northwestern University.

“I think one of the most valuable aspects of the MICRO program is the ability to do research long term with an experienced professor in materials science and engineering,” says Wood. “My school has limited opportunities for undergraduate research in sustainable polymers, so the MICRO program allowed me to gain valuable experience in this field, which I would not otherwise have.”

Like Wood, Griheydi Garcia, a senior chemistry major at Manhattan College, values the exposure to materials science, especially since she is not able to learn as much about it at her home institution.

“I learned a lot about crystallography and defects in materials through the MICRO curriculum, especially through videos,” says Garcia. “The research itself is very valuable, as well, because we get to apply what we’ve learned through the videos in the research we do remotely.”

Expanding research opportunities

From the beginning, the MICRO program was designed as a fully remote, rigorous education and mentoring program targeted toward students from underserved backgrounds interested in pursuing graduate school in materials science or related fields. Interns are matched with faculty to work on their specific research interests.

Jessica Sandland ’99, PhD ’05, principal lecturer in DMSE and co-founder of MICRO, says that research projects for the interns are designed to be work that they can do remotely, such as developing a machine-learning algorithm or a data analysis approach.

“It’s important to note that it’s not just about what the program and faculty are bringing to the student interns,” says Sandland, a member of the MIT Digital Learning Lab, a joint program between MIT Open Learning and the Institute’s academic departments. “The students are doing real research and work, and creating things of real value. It’s very much an exchange.”

Cécile Chazot PhD ’22, now an assistant professor of materials science and engineering at Northwestern University, had helped to establish MICRO at MIT from the very beginning. Once at Northwestern, she quickly realized that expanding MICRO to Northwestern would offer even more research opportunities to interns than by relying on MIT alone — leveraging the university’s strong materials science and engineering department, as well as offering resources for biomaterials research through Northwestern’s medical school. The program received funding from 3M and officially launched at Northwestern in fall 2023. Approximately half of the MICRO interns are now in the program with MIT and half are with Northwestern. Wood and Garcia both participate in the program via Northwestern.

“By expanding to another school, we’ve been able to have interns work with a much broader range of research projects,” says Chazot. “It has become easier for us to place students with faculty and research that match their interests.”

Building community

The MICRO program received a Higher Education Innovation grant from the Abdul Latif Jameel World Education Lab, part of MIT Open Learning, to develop an in-person summit. In January 2024, interns visited MIT for three days of presentations, workshops, and campus tours — including a tour of the MIT.nano building — as well as various community-building activities.

“A big part of MICRO is the community,” says Chazot. “A highlight of the summit was just seeing the students come together.”

The summit also included panel discussions that allowed interns to gain insights and advice from graduate students and professionals. The graduate panel discussion included MIT graduate students Sam Figueroa (mechanical engineering), Isabella Caruso (DMSE), and Eliana Feygin (DMSE). The career panel was led by Chazot and included Jatin Patil PhD ’23, head of product at SiTration; Maureen Reitman ’90, ScD ’93, group vice president and principal engineer at Exponent; Lucas Caretta PhD ’19, assistant professor of engineering at Brown University; Raquel D’Oyen ’90, who holds a PhD from Northwestern University and is a senior engineer at Raytheon; and Ashley Kaiser MS ’19, PhD ’21, senior process engineer at 6K.

Students also had an opportunity to share their work with each other through research presentations. Their presentations covered a wide range of topics, including: developing a computer program to calculate solubility parameters for polymers used in textile manufacturing; performing a life-cycle analysis of a photonic chip and evaluating its environmental impact in comparison to a standard silicon microchip; and applying machine learning algorithms to scanning transmission electron microscopy images of CrSBr, a two-dimensional magnetic material. 

“The summit was wonderful and the best academic experience I have had as a first-year college student,” says MICRO intern Gabriella La Cour, who is pursuing a major in chemistry and dual degree biomedical engineering at Spelman College and participates in MICRO through MIT. “I got to meet so many students who were all in grades above me … and I learned a little about how to navigate college as an upperclassman.” 

“I actually have an extremely close friendship with one of the students, and we keep in touch regularly,” adds La Cour. “Professor Chazot gave valuable advice about applications and recommendation letters that will be useful when I apply to REUs [Research Experiences for Undergraduates] and graduate schools.”

Looking to the future, MICRO organizers hope to continue to grow the program’s reach.

“We would love to see other schools taking on this model,” says Sandland. “There are a lot of opportunities out there. The more departments, research groups, and mentors that get involved with this program, the more impact it can have.”

© Photo courtesy of the DMSE

Ten undergraduates from 10 universities around the United States visited MIT to participate in the first MICRO Summit earlier this year. Pictured are the student interns, organizers, and the career panelists.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.

Fostering research, careers, and community in materials science

Gabrielle Wood, a junior at Howard University majoring in chemical engineering, is on a mission to improve the sustainability and life cycles of natural resources and materials. Her work in the Materials Initiative for Comprehensive Research Opportunity (MICRO) program has given her hands-on experience with many different aspects of research, including MATLAB programming, experimental design, data analysis, figure-making, and scientific writing.

Wood is also one of 10 undergraduates from 10 universities around the United States to participate in the first MICRO Summit earlier this year. The internship program, developed by the MIT Department of Materials Science and Engineering (DMSE), first launched in fall 2021. Now in its third year, the program continues to grow, providing even more opportunities for non-MIT undergraduate students — including the MICRO Summit and the program’s expansion to include Northwestern University.

“I think one of the most valuable aspects of the MICRO program is the ability to do research long term with an experienced professor in materials science and engineering,” says Wood. “My school has limited opportunities for undergraduate research in sustainable polymers, so the MICRO program allowed me to gain valuable experience in this field, which I would not otherwise have.”

Like Wood, Griheydi Garcia, a senior chemistry major at Manhattan College, values the exposure to materials science, especially since she is not able to learn as much about it at her home institution.

“I learned a lot about crystallography and defects in materials through the MICRO curriculum, especially through videos,” says Garcia. “The research itself is very valuable, as well, because we get to apply what we’ve learned through the videos in the research we do remotely.”

Expanding research opportunities

From the beginning, the MICRO program was designed as a fully remote, rigorous education and mentoring program targeted toward students from underserved backgrounds interested in pursuing graduate school in materials science or related fields. Interns are matched with faculty to work on their specific research interests.

Jessica Sandland ’99, PhD ’05, principal lecturer in DMSE and co-founder of MICRO, says that research projects for the interns are designed to be work that they can do remotely, such as developing a machine-learning algorithm or a data analysis approach.

“It’s important to note that it’s not just about what the program and faculty are bringing to the student interns,” says Sandland, a member of the MIT Digital Learning Lab, a joint program between MIT Open Learning and the Institute’s academic departments. “The students are doing real research and work, and creating things of real value. It’s very much an exchange.”

Cécile Chazot PhD ’22, now an assistant professor of materials science and engineering at Northwestern University, had helped to establish MICRO at MIT from the very beginning. Once at Northwestern, she quickly realized that expanding MICRO to Northwestern would offer even more research opportunities to interns than by relying on MIT alone — leveraging the university’s strong materials science and engineering department, as well as offering resources for biomaterials research through Northwestern’s medical school. The program received funding from 3M and officially launched at Northwestern in fall 2023. Approximately half of the MICRO interns are now in the program with MIT and half are with Northwestern. Wood and Garcia both participate in the program via Northwestern.

“By expanding to another school, we’ve been able to have interns work with a much broader range of research projects,” says Chazot. “It has become easier for us to place students with faculty and research that match their interests.”

Building community

The MICRO program received a Higher Education Innovation grant from the Abdul Latif Jameel World Education Lab, part of MIT Open Learning, to develop an in-person summit. In January 2024, interns visited MIT for three days of presentations, workshops, and campus tours — including a tour of the MIT.nano building — as well as various community-building activities.

“A big part of MICRO is the community,” says Chazot. “A highlight of the summit was just seeing the students come together.”

The summit also included panel discussions that allowed interns to gain insights and advice from graduate students and professionals. The graduate panel discussion included MIT graduate students Sam Figueroa (mechanical engineering), Isabella Caruso (DMSE), and Eliana Feygin (DMSE). The career panel was led by Chazot and included Jatin Patil PhD ’23, head of product at SiTration; Maureen Reitman ’90, ScD ’93, group vice president and principal engineer at Exponent; Lucas Caretta PhD ’19, assistant professor of engineering at Brown University; Raquel D’Oyen ’90, who holds a PhD from Northwestern University and is a senior engineer at Raytheon; and Ashley Kaiser MS ’19, PhD ’21, senior process engineer at 6K.

Students also had an opportunity to share their work with each other through research presentations. Their presentations covered a wide range of topics, including: developing a computer program to calculate solubility parameters for polymers used in textile manufacturing; performing a life-cycle analysis of a photonic chip and evaluating its environmental impact in comparison to a standard silicon microchip; and applying machine learning algorithms to scanning transmission electron microscopy images of CrSBr, a two-dimensional magnetic material. 

“The summit was wonderful and the best academic experience I have had as a first-year college student,” says MICRO intern Gabriella La Cour, who is pursuing a major in chemistry and dual degree biomedical engineering at Spelman College and participates in MICRO through MIT. “I got to meet so many students who were all in grades above me … and I learned a little about how to navigate college as an upperclassman.” 

“I actually have an extremely close friendship with one of the students, and we keep in touch regularly,” adds La Cour. “Professor Chazot gave valuable advice about applications and recommendation letters that will be useful when I apply to REUs [Research Experiences for Undergraduates] and graduate schools.”

Looking to the future, MICRO organizers hope to continue to grow the program’s reach.

“We would love to see other schools taking on this model,” says Sandland. “There are a lot of opportunities out there. The more departments, research groups, and mentors that get involved with this program, the more impact it can have.”

© Photo courtesy of the DMSE

Ten undergraduates from 10 universities around the United States visited MIT to participate in the first MICRO Summit earlier this year. Pictured are the student interns, organizers, and the career panelists.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.

Fostering research, careers, and community in materials science

Gabrielle Wood, a junior at Howard University majoring in chemical engineering, is on a mission to improve the sustainability and life cycles of natural resources and materials. Her work in the Materials Initiative for Comprehensive Research Opportunity (MICRO) program has given her hands-on experience with many different aspects of research, including MATLAB programming, experimental design, data analysis, figure-making, and scientific writing.

Wood is also one of 10 undergraduates from 10 universities around the United States to participate in the first MICRO Summit earlier this year. The internship program, developed by the MIT Department of Materials Science and Engineering (DMSE), first launched in fall 2021. Now in its third year, the program continues to grow, providing even more opportunities for non-MIT undergraduate students — including the MICRO Summit and the program’s expansion to include Northwestern University.

“I think one of the most valuable aspects of the MICRO program is the ability to do research long term with an experienced professor in materials science and engineering,” says Wood. “My school has limited opportunities for undergraduate research in sustainable polymers, so the MICRO program allowed me to gain valuable experience in this field, which I would not otherwise have.”

Like Wood, Griheydi Garcia, a senior chemistry major at Manhattan College, values the exposure to materials science, especially since she is not able to learn as much about it at her home institution.

“I learned a lot about crystallography and defects in materials through the MICRO curriculum, especially through videos,” says Garcia. “The research itself is very valuable, as well, because we get to apply what we’ve learned through the videos in the research we do remotely.”

Expanding research opportunities

From the beginning, the MICRO program was designed as a fully remote, rigorous education and mentoring program targeted toward students from underserved backgrounds interested in pursuing graduate school in materials science or related fields. Interns are matched with faculty to work on their specific research interests.

Jessica Sandland ’99, PhD ’05, principal lecturer in DMSE and co-founder of MICRO, says that research projects for the interns are designed to be work that they can do remotely, such as developing a machine-learning algorithm or a data analysis approach.

“It’s important to note that it’s not just about what the program and faculty are bringing to the student interns,” says Sandland, a member of the MIT Digital Learning Lab, a joint program between MIT Open Learning and the Institute’s academic departments. “The students are doing real research and work, and creating things of real value. It’s very much an exchange.”

Cécile Chazot PhD ’22, now an assistant professor of materials science and engineering at Northwestern University, had helped to establish MICRO at MIT from the very beginning. Once at Northwestern, she quickly realized that expanding MICRO to Northwestern would offer even more research opportunities to interns than by relying on MIT alone — leveraging the university’s strong materials science and engineering department, as well as offering resources for biomaterials research through Northwestern’s medical school. The program received funding from 3M and officially launched at Northwestern in fall 2023. Approximately half of the MICRO interns are now in the program with MIT and half are with Northwestern. Wood and Garcia both participate in the program via Northwestern.

“By expanding to another school, we’ve been able to have interns work with a much broader range of research projects,” says Chazot. “It has become easier for us to place students with faculty and research that match their interests.”

Building community

The MICRO program received a Higher Education Innovation grant from the Abdul Latif Jameel World Education Lab, part of MIT Open Learning, to develop an in-person summit. In January 2024, interns visited MIT for three days of presentations, workshops, and campus tours — including a tour of the MIT.nano building — as well as various community-building activities.

“A big part of MICRO is the community,” says Chazot. “A highlight of the summit was just seeing the students come together.”

The summit also included panel discussions that allowed interns to gain insights and advice from graduate students and professionals. The graduate panel discussion included MIT graduate students Sam Figueroa (mechanical engineering), Isabella Caruso (DMSE), and Eliana Feygin (DMSE). The career panel was led by Chazot and included Jatin Patil PhD ’23, head of product at SiTration; Maureen Reitman ’90, ScD ’93, group vice president and principal engineer at Exponent; Lucas Caretta PhD ’19, assistant professor of engineering at Brown University; Raquel D’Oyen ’90, who holds a PhD from Northwestern University and is a senior engineer at Raytheon; and Ashley Kaiser MS ’19, PhD ’21, senior process engineer at 6K.

Students also had an opportunity to share their work with each other through research presentations. Their presentations covered a wide range of topics, including: developing a computer program to calculate solubility parameters for polymers used in textile manufacturing; performing a life-cycle analysis of a photonic chip and evaluating its environmental impact in comparison to a standard silicon microchip; and applying machine learning algorithms to scanning transmission electron microscopy images of CrSBr, a two-dimensional magnetic material. 

“The summit was wonderful and the best academic experience I have had as a first-year college student,” says MICRO intern Gabriella La Cour, who is pursuing a major in chemistry and dual degree biomedical engineering at Spelman College and participates in MICRO through MIT. “I got to meet so many students who were all in grades above me … and I learned a little about how to navigate college as an upperclassman.” 

“I actually have an extremely close friendship with one of the students, and we keep in touch regularly,” adds La Cour. “Professor Chazot gave valuable advice about applications and recommendation letters that will be useful when I apply to REUs [Research Experiences for Undergraduates] and graduate schools.”

Looking to the future, MICRO organizers hope to continue to grow the program’s reach.

“We would love to see other schools taking on this model,” says Sandland. “There are a lot of opportunities out there. The more departments, research groups, and mentors that get involved with this program, the more impact it can have.”

© Photo courtesy of the DMSE

Ten undergraduates from 10 universities around the United States visited MIT to participate in the first MICRO Summit earlier this year. Pictured are the student interns, organizers, and the career panelists.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.

Fostering research, careers, and community in materials science

Gabrielle Wood, a junior at Howard University majoring in chemical engineering, is on a mission to improve the sustainability and life cycles of natural resources and materials. Her work in the Materials Initiative for Comprehensive Research Opportunity (MICRO) program has given her hands-on experience with many different aspects of research, including MATLAB programming, experimental design, data analysis, figure-making, and scientific writing.

Wood is also one of 10 undergraduates from 10 universities around the United States to participate in the first MICRO Summit earlier this year. The internship program, developed by the MIT Department of Materials Science and Engineering (DMSE), first launched in fall 2021. Now in its third year, the program continues to grow, providing even more opportunities for non-MIT undergraduate students — including the MICRO Summit and the program’s expansion to include Northwestern University.

“I think one of the most valuable aspects of the MICRO program is the ability to do research long term with an experienced professor in materials science and engineering,” says Wood. “My school has limited opportunities for undergraduate research in sustainable polymers, so the MICRO program allowed me to gain valuable experience in this field, which I would not otherwise have.”

Like Wood, Griheydi Garcia, a senior chemistry major at Manhattan College, values the exposure to materials science, especially since she is not able to learn as much about it at her home institution.

“I learned a lot about crystallography and defects in materials through the MICRO curriculum, especially through videos,” says Garcia. “The research itself is very valuable, as well, because we get to apply what we’ve learned through the videos in the research we do remotely.”

Expanding research opportunities

From the beginning, the MICRO program was designed as a fully remote, rigorous education and mentoring program targeted toward students from underserved backgrounds interested in pursuing graduate school in materials science or related fields. Interns are matched with faculty to work on their specific research interests.

Jessica Sandland ’99, PhD ’05, principal lecturer in DMSE and co-founder of MICRO, says that research projects for the interns are designed to be work that they can do remotely, such as developing a machine-learning algorithm or a data analysis approach.

“It’s important to note that it’s not just about what the program and faculty are bringing to the student interns,” says Sandland, a member of the MIT Digital Learning Lab, a joint program between MIT Open Learning and the Institute’s academic departments. “The students are doing real research and work, and creating things of real value. It’s very much an exchange.”

Cécile Chazot PhD ’22, now an assistant professor of materials science and engineering at Northwestern University, had helped to establish MICRO at MIT from the very beginning. Once at Northwestern, she quickly realized that expanding MICRO to Northwestern would offer even more research opportunities to interns than by relying on MIT alone — leveraging the university’s strong materials science and engineering department, as well as offering resources for biomaterials research through Northwestern’s medical school. The program received funding from 3M and officially launched at Northwestern in fall 2023. Approximately half of the MICRO interns are now in the program with MIT and half are with Northwestern. Wood and Garcia both participate in the program via Northwestern.

“By expanding to another school, we’ve been able to have interns work with a much broader range of research projects,” says Chazot. “It has become easier for us to place students with faculty and research that match their interests.”

Building community

The MICRO program received a Higher Education Innovation grant from the Abdul Latif Jameel World Education Lab, part of MIT Open Learning, to develop an in-person summit. In January 2024, interns visited MIT for three days of presentations, workshops, and campus tours — including a tour of the MIT.nano building — as well as various community-building activities.

“A big part of MICRO is the community,” says Chazot. “A highlight of the summit was just seeing the students come together.”

The summit also included panel discussions that allowed interns to gain insights and advice from graduate students and professionals. The graduate panel discussion included MIT graduate students Sam Figueroa (mechanical engineering), Isabella Caruso (DMSE), and Eliana Feygin (DMSE). The career panel was led by Chazot and included Jatin Patil PhD ’23, head of product at SiTration; Maureen Reitman ’90, ScD ’93, group vice president and principal engineer at Exponent; Lucas Caretta PhD ’19, assistant professor of engineering at Brown University; Raquel D’Oyen ’90, who holds a PhD from Northwestern University and is a senior engineer at Raytheon; and Ashley Kaiser MS ’19, PhD ’21, senior process engineer at 6K.

Students also had an opportunity to share their work with each other through research presentations. Their presentations covered a wide range of topics, including: developing a computer program to calculate solubility parameters for polymers used in textile manufacturing; performing a life-cycle analysis of a photonic chip and evaluating its environmental impact in comparison to a standard silicon microchip; and applying machine learning algorithms to scanning transmission electron microscopy images of CrSBr, a two-dimensional magnetic material. 

“The summit was wonderful and the best academic experience I have had as a first-year college student,” says MICRO intern Gabriella La Cour, who is pursuing a major in chemistry and dual degree biomedical engineering at Spelman College and participates in MICRO through MIT. “I got to meet so many students who were all in grades above me … and I learned a little about how to navigate college as an upperclassman.” 

“I actually have an extremely close friendship with one of the students, and we keep in touch regularly,” adds La Cour. “Professor Chazot gave valuable advice about applications and recommendation letters that will be useful when I apply to REUs [Research Experiences for Undergraduates] and graduate schools.”

Looking to the future, MICRO organizers hope to continue to grow the program’s reach.

“We would love to see other schools taking on this model,” says Sandland. “There are a lot of opportunities out there. The more departments, research groups, and mentors that get involved with this program, the more impact it can have.”

© Photo courtesy of the DMSE

Ten undergraduates from 10 universities around the United States visited MIT to participate in the first MICRO Summit earlier this year. Pictured are the student interns, organizers, and the career panelists.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.

Fostering research, careers, and community in materials science

Gabrielle Wood, a junior at Howard University majoring in chemical engineering, is on a mission to improve the sustainability and life cycles of natural resources and materials. Her work in the Materials Initiative for Comprehensive Research Opportunity (MICRO) program has given her hands-on experience with many different aspects of research, including MATLAB programming, experimental design, data analysis, figure-making, and scientific writing.

Wood is also one of 10 undergraduates from 10 universities around the United States to participate in the first MICRO Summit earlier this year. The internship program, developed by the MIT Department of Materials Science and Engineering (DMSE), first launched in fall 2021. Now in its third year, the program continues to grow, providing even more opportunities for non-MIT undergraduate students — including the MICRO Summit and the program’s expansion to include Northwestern University.

“I think one of the most valuable aspects of the MICRO program is the ability to do research long term with an experienced professor in materials science and engineering,” says Wood. “My school has limited opportunities for undergraduate research in sustainable polymers, so the MICRO program allowed me to gain valuable experience in this field, which I would not otherwise have.”

Like Wood, Griheydi Garcia, a senior chemistry major at Manhattan College, values the exposure to materials science, especially since she is not able to learn as much about it at her home institution.

“I learned a lot about crystallography and defects in materials through the MICRO curriculum, especially through videos,” says Garcia. “The research itself is very valuable, as well, because we get to apply what we’ve learned through the videos in the research we do remotely.”

Expanding research opportunities

From the beginning, the MICRO program was designed as a fully remote, rigorous education and mentoring program targeted toward students from underserved backgrounds interested in pursuing graduate school in materials science or related fields. Interns are matched with faculty to work on their specific research interests.

Jessica Sandland ’99, PhD ’05, principal lecturer in DMSE and co-founder of MICRO, says that research projects for the interns are designed to be work that they can do remotely, such as developing a machine-learning algorithm or a data analysis approach.

“It’s important to note that it’s not just about what the program and faculty are bringing to the student interns,” says Sandland, a member of the MIT Digital Learning Lab, a joint program between MIT Open Learning and the Institute’s academic departments. “The students are doing real research and work, and creating things of real value. It’s very much an exchange.”

Cécile Chazot PhD ’22, now an assistant professor of materials science and engineering at Northwestern University, had helped to establish MICRO at MIT from the very beginning. Once at Northwestern, she quickly realized that expanding MICRO to Northwestern would offer even more research opportunities to interns than by relying on MIT alone — leveraging the university’s strong materials science and engineering department, as well as offering resources for biomaterials research through Northwestern’s medical school. The program received funding from 3M and officially launched at Northwestern in fall 2023. Approximately half of the MICRO interns are now in the program with MIT and half are with Northwestern. Wood and Garcia both participate in the program via Northwestern.

“By expanding to another school, we’ve been able to have interns work with a much broader range of research projects,” says Chazot. “It has become easier for us to place students with faculty and research that match their interests.”

Building community

The MICRO program received a Higher Education Innovation grant from the Abdul Latif Jameel World Education Lab, part of MIT Open Learning, to develop an in-person summit. In January 2024, interns visited MIT for three days of presentations, workshops, and campus tours — including a tour of the MIT.nano building — as well as various community-building activities.

“A big part of MICRO is the community,” says Chazot. “A highlight of the summit was just seeing the students come together.”

The summit also included panel discussions that allowed interns to gain insights and advice from graduate students and professionals. The graduate panel discussion included MIT graduate students Sam Figueroa (mechanical engineering), Isabella Caruso (DMSE), and Eliana Feygin (DMSE). The career panel was led by Chazot and included Jatin Patil PhD ’23, head of product at SiTration; Maureen Reitman ’90, ScD ’93, group vice president and principal engineer at Exponent; Lucas Caretta PhD ’19, assistant professor of engineering at Brown University; Raquel D’Oyen ’90, who holds a PhD from Northwestern University and is a senior engineer at Raytheon; and Ashley Kaiser MS ’19, PhD ’21, senior process engineer at 6K.

Students also had an opportunity to share their work with each other through research presentations. Their presentations covered a wide range of topics, including: developing a computer program to calculate solubility parameters for polymers used in textile manufacturing; performing a life-cycle analysis of a photonic chip and evaluating its environmental impact in comparison to a standard silicon microchip; and applying machine learning algorithms to scanning transmission electron microscopy images of CrSBr, a two-dimensional magnetic material. 

“The summit was wonderful and the best academic experience I have had as a first-year college student,” says MICRO intern Gabriella La Cour, who is pursuing a major in chemistry and dual degree biomedical engineering at Spelman College and participates in MICRO through MIT. “I got to meet so many students who were all in grades above me … and I learned a little about how to navigate college as an upperclassman.” 

“I actually have an extremely close friendship with one of the students, and we keep in touch regularly,” adds La Cour. “Professor Chazot gave valuable advice about applications and recommendation letters that will be useful when I apply to REUs [Research Experiences for Undergraduates] and graduate schools.”

Looking to the future, MICRO organizers hope to continue to grow the program’s reach.

“We would love to see other schools taking on this model,” says Sandland. “There are a lot of opportunities out there. The more departments, research groups, and mentors that get involved with this program, the more impact it can have.”

© Photo courtesy of the DMSE

Ten undergraduates from 10 universities around the United States visited MIT to participate in the first MICRO Summit earlier this year. Pictured are the student interns, organizers, and the career panelists.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.

Fostering research, careers, and community in materials science

Gabrielle Wood, a junior at Howard University majoring in chemical engineering, is on a mission to improve the sustainability and life cycles of natural resources and materials. Her work in the Materials Initiative for Comprehensive Research Opportunity (MICRO) program has given her hands-on experience with many different aspects of research, including MATLAB programming, experimental design, data analysis, figure-making, and scientific writing.

Wood is also one of 10 undergraduates from 10 universities around the United States to participate in the first MICRO Summit earlier this year. The internship program, developed by the MIT Department of Materials Science and Engineering (DMSE), first launched in fall 2021. Now in its third year, the program continues to grow, providing even more opportunities for non-MIT undergraduate students — including the MICRO Summit and the program’s expansion to include Northwestern University.

“I think one of the most valuable aspects of the MICRO program is the ability to do research long term with an experienced professor in materials science and engineering,” says Wood. “My school has limited opportunities for undergraduate research in sustainable polymers, so the MICRO program allowed me to gain valuable experience in this field, which I would not otherwise have.”

Like Wood, Griheydi Garcia, a senior chemistry major at Manhattan College, values the exposure to materials science, especially since she is not able to learn as much about it at her home institution.

“I learned a lot about crystallography and defects in materials through the MICRO curriculum, especially through videos,” says Garcia. “The research itself is very valuable, as well, because we get to apply what we’ve learned through the videos in the research we do remotely.”

Expanding research opportunities

From the beginning, the MICRO program was designed as a fully remote, rigorous education and mentoring program targeted toward students from underserved backgrounds interested in pursuing graduate school in materials science or related fields. Interns are matched with faculty to work on their specific research interests.

Jessica Sandland ’99, PhD ’05, principal lecturer in DMSE and co-founder of MICRO, says that research projects for the interns are designed to be work that they can do remotely, such as developing a machine-learning algorithm or a data analysis approach.

“It’s important to note that it’s not just about what the program and faculty are bringing to the student interns,” says Sandland, a member of the MIT Digital Learning Lab, a joint program between MIT Open Learning and the Institute’s academic departments. “The students are doing real research and work, and creating things of real value. It’s very much an exchange.”

Cécile Chazot PhD ’22, now an assistant professor of materials science and engineering at Northwestern University, had helped to establish MICRO at MIT from the very beginning. Once at Northwestern, she quickly realized that expanding MICRO to Northwestern would offer even more research opportunities to interns than by relying on MIT alone — leveraging the university’s strong materials science and engineering department, as well as offering resources for biomaterials research through Northwestern’s medical school. The program received funding from 3M and officially launched at Northwestern in fall 2023. Approximately half of the MICRO interns are now in the program with MIT and half are with Northwestern. Wood and Garcia both participate in the program via Northwestern.

“By expanding to another school, we’ve been able to have interns work with a much broader range of research projects,” says Chazot. “It has become easier for us to place students with faculty and research that match their interests.”

Building community

The MICRO program received a Higher Education Innovation grant from the Abdul Latif Jameel World Education Lab, part of MIT Open Learning, to develop an in-person summit. In January 2024, interns visited MIT for three days of presentations, workshops, and campus tours — including a tour of the MIT.nano building — as well as various community-building activities.

“A big part of MICRO is the community,” says Chazot. “A highlight of the summit was just seeing the students come together.”

The summit also included panel discussions that allowed interns to gain insights and advice from graduate students and professionals. The graduate panel discussion included MIT graduate students Sam Figueroa (mechanical engineering), Isabella Caruso (DMSE), and Eliana Feygin (DMSE). The career panel was led by Chazot and included Jatin Patil PhD ’23, head of product at SiTration; Maureen Reitman ’90, ScD ’93, group vice president and principal engineer at Exponent; Lucas Caretta PhD ’19, assistant professor of engineering at Brown University; Raquel D’Oyen ’90, who holds a PhD from Northwestern University and is a senior engineer at Raytheon; and Ashley Kaiser MS ’19, PhD ’21, senior process engineer at 6K.

Students also had an opportunity to share their work with each other through research presentations. Their presentations covered a wide range of topics, including: developing a computer program to calculate solubility parameters for polymers used in textile manufacturing; performing a life-cycle analysis of a photonic chip and evaluating its environmental impact in comparison to a standard silicon microchip; and applying machine learning algorithms to scanning transmission electron microscopy images of CrSBr, a two-dimensional magnetic material. 

“The summit was wonderful and the best academic experience I have had as a first-year college student,” says MICRO intern Gabriella La Cour, who is pursuing a major in chemistry and dual degree biomedical engineering at Spelman College and participates in MICRO through MIT. “I got to meet so many students who were all in grades above me … and I learned a little about how to navigate college as an upperclassman.” 

“I actually have an extremely close friendship with one of the students, and we keep in touch regularly,” adds La Cour. “Professor Chazot gave valuable advice about applications and recommendation letters that will be useful when I apply to REUs [Research Experiences for Undergraduates] and graduate schools.”

Looking to the future, MICRO organizers hope to continue to grow the program’s reach.

“We would love to see other schools taking on this model,” says Sandland. “There are a lot of opportunities out there. The more departments, research groups, and mentors that get involved with this program, the more impact it can have.”

© Photo courtesy of the DMSE

Ten undergraduates from 10 universities around the United States visited MIT to participate in the first MICRO Summit earlier this year. Pictured are the student interns, organizers, and the career panelists.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.

Fostering research, careers, and community in materials science

Gabrielle Wood, a junior at Howard University majoring in chemical engineering, is on a mission to improve the sustainability and life cycles of natural resources and materials. Her work in the Materials Initiative for Comprehensive Research Opportunity (MICRO) program has given her hands-on experience with many different aspects of research, including MATLAB programming, experimental design, data analysis, figure-making, and scientific writing.

Wood is also one of 10 undergraduates from 10 universities around the United States to participate in the first MICRO Summit earlier this year. The internship program, developed by the MIT Department of Materials Science and Engineering (DMSE), first launched in fall 2021. Now in its third year, the program continues to grow, providing even more opportunities for non-MIT undergraduate students — including the MICRO Summit and the program’s expansion to include Northwestern University.

“I think one of the most valuable aspects of the MICRO program is the ability to do research long term with an experienced professor in materials science and engineering,” says Wood. “My school has limited opportunities for undergraduate research in sustainable polymers, so the MICRO program allowed me to gain valuable experience in this field, which I would not otherwise have.”

Like Wood, Griheydi Garcia, a senior chemistry major at Manhattan College, values the exposure to materials science, especially since she is not able to learn as much about it at her home institution.

“I learned a lot about crystallography and defects in materials through the MICRO curriculum, especially through videos,” says Garcia. “The research itself is very valuable, as well, because we get to apply what we’ve learned through the videos in the research we do remotely.”

Expanding research opportunities

From the beginning, the MICRO program was designed as a fully remote, rigorous education and mentoring program targeted toward students from underserved backgrounds interested in pursuing graduate school in materials science or related fields. Interns are matched with faculty to work on their specific research interests.

Jessica Sandland ’99, PhD ’05, principal lecturer in DMSE and co-founder of MICRO, says that research projects for the interns are designed to be work that they can do remotely, such as developing a machine-learning algorithm or a data analysis approach.

“It’s important to note that it’s not just about what the program and faculty are bringing to the student interns,” says Sandland, a member of the MIT Digital Learning Lab, a joint program between MIT Open Learning and the Institute’s academic departments. “The students are doing real research and work, and creating things of real value. It’s very much an exchange.”

Cécile Chazot PhD ’22, now an assistant professor of materials science and engineering at Northwestern University, had helped to establish MICRO at MIT from the very beginning. Once at Northwestern, she quickly realized that expanding MICRO to Northwestern would offer even more research opportunities to interns than by relying on MIT alone — leveraging the university’s strong materials science and engineering department, as well as offering resources for biomaterials research through Northwestern’s medical school. The program received funding from 3M and officially launched at Northwestern in fall 2023. Approximately half of the MICRO interns are now in the program with MIT and half are with Northwestern. Wood and Garcia both participate in the program via Northwestern.

“By expanding to another school, we’ve been able to have interns work with a much broader range of research projects,” says Chazot. “It has become easier for us to place students with faculty and research that match their interests.”

Building community

The MICRO program received a Higher Education Innovation grant from the Abdul Latif Jameel World Education Lab, part of MIT Open Learning, to develop an in-person summit. In January 2024, interns visited MIT for three days of presentations, workshops, and campus tours — including a tour of the MIT.nano building — as well as various community-building activities.

“A big part of MICRO is the community,” says Chazot. “A highlight of the summit was just seeing the students come together.”

The summit also included panel discussions that allowed interns to gain insights and advice from graduate students and professionals. The graduate panel discussion included MIT graduate students Sam Figueroa (mechanical engineering), Isabella Caruso (DMSE), and Eliana Feygin (DMSE). The career panel was led by Chazot and included Jatin Patil PhD ’23, head of product at SiTration; Maureen Reitman ’90, ScD ’93, group vice president and principal engineer at Exponent; Lucas Caretta PhD ’19, assistant professor of engineering at Brown University; Raquel D’Oyen ’90, who holds a PhD from Northwestern University and is a senior engineer at Raytheon; and Ashley Kaiser MS ’19, PhD ’21, senior process engineer at 6K.

Students also had an opportunity to share their work with each other through research presentations. Their presentations covered a wide range of topics, including: developing a computer program to calculate solubility parameters for polymers used in textile manufacturing; performing a life-cycle analysis of a photonic chip and evaluating its environmental impact in comparison to a standard silicon microchip; and applying machine learning algorithms to scanning transmission electron microscopy images of CrSBr, a two-dimensional magnetic material. 

“The summit was wonderful and the best academic experience I have had as a first-year college student,” says MICRO intern Gabriella La Cour, who is pursuing a major in chemistry and dual degree biomedical engineering at Spelman College and participates in MICRO through MIT. “I got to meet so many students who were all in grades above me … and I learned a little about how to navigate college as an upperclassman.” 

“I actually have an extremely close friendship with one of the students, and we keep in touch regularly,” adds La Cour. “Professor Chazot gave valuable advice about applications and recommendation letters that will be useful when I apply to REUs [Research Experiences for Undergraduates] and graduate schools.”

Looking to the future, MICRO organizers hope to continue to grow the program’s reach.

“We would love to see other schools taking on this model,” says Sandland. “There are a lot of opportunities out there. The more departments, research groups, and mentors that get involved with this program, the more impact it can have.”

© Photo courtesy of the DMSE

Ten undergraduates from 10 universities around the United States visited MIT to participate in the first MICRO Summit earlier this year. Pictured are the student interns, organizers, and the career panelists.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.

Fostering research, careers, and community in materials science

Gabrielle Wood, a junior at Howard University majoring in chemical engineering, is on a mission to improve the sustainability and life cycles of natural resources and materials. Her work in the Materials Initiative for Comprehensive Research Opportunity (MICRO) program has given her hands-on experience with many different aspects of research, including MATLAB programming, experimental design, data analysis, figure-making, and scientific writing.

Wood is also one of 10 undergraduates from 10 universities around the United States to participate in the first MICRO Summit earlier this year. The internship program, developed by the MIT Department of Materials Science and Engineering (DMSE), first launched in fall 2021. Now in its third year, the program continues to grow, providing even more opportunities for non-MIT undergraduate students — including the MICRO Summit and the program’s expansion to include Northwestern University.

“I think one of the most valuable aspects of the MICRO program is the ability to do research long term with an experienced professor in materials science and engineering,” says Wood. “My school has limited opportunities for undergraduate research in sustainable polymers, so the MICRO program allowed me to gain valuable experience in this field, which I would not otherwise have.”

Like Wood, Griheydi Garcia, a senior chemistry major at Manhattan College, values the exposure to materials science, especially since she is not able to learn as much about it at her home institution.

“I learned a lot about crystallography and defects in materials through the MICRO curriculum, especially through videos,” says Garcia. “The research itself is very valuable, as well, because we get to apply what we’ve learned through the videos in the research we do remotely.”

Expanding research opportunities

From the beginning, the MICRO program was designed as a fully remote, rigorous education and mentoring program targeted toward students from underserved backgrounds interested in pursuing graduate school in materials science or related fields. Interns are matched with faculty to work on their specific research interests.

Jessica Sandland ’99, PhD ’05, principal lecturer in DMSE and co-founder of MICRO, says that research projects for the interns are designed to be work that they can do remotely, such as developing a machine-learning algorithm or a data analysis approach.

“It’s important to note that it’s not just about what the program and faculty are bringing to the student interns,” says Sandland, a member of the MIT Digital Learning Lab, a joint program between MIT Open Learning and the Institute’s academic departments. “The students are doing real research and work, and creating things of real value. It’s very much an exchange.”

Cécile Chazot PhD ’22, now an assistant professor of materials science and engineering at Northwestern University, had helped to establish MICRO at MIT from the very beginning. Once at Northwestern, she quickly realized that expanding MICRO to Northwestern would offer even more research opportunities to interns than by relying on MIT alone — leveraging the university’s strong materials science and engineering department, as well as offering resources for biomaterials research through Northwestern’s medical school. The program received funding from 3M and officially launched at Northwestern in fall 2023. Approximately half of the MICRO interns are now in the program with MIT and half are with Northwestern. Wood and Garcia both participate in the program via Northwestern.

“By expanding to another school, we’ve been able to have interns work with a much broader range of research projects,” says Chazot. “It has become easier for us to place students with faculty and research that match their interests.”

Building community

The MICRO program received a Higher Education Innovation grant from the Abdul Latif Jameel World Education Lab, part of MIT Open Learning, to develop an in-person summit. In January 2024, interns visited MIT for three days of presentations, workshops, and campus tours — including a tour of the MIT.nano building — as well as various community-building activities.

“A big part of MICRO is the community,” says Chazot. “A highlight of the summit was just seeing the students come together.”

The summit also included panel discussions that allowed interns to gain insights and advice from graduate students and professionals. The graduate panel discussion included MIT graduate students Sam Figueroa (mechanical engineering), Isabella Caruso (DMSE), and Eliana Feygin (DMSE). The career panel was led by Chazot and included Jatin Patil PhD ’23, head of product at SiTration; Maureen Reitman ’90, ScD ’93, group vice president and principal engineer at Exponent; Lucas Caretta PhD ’19, assistant professor of engineering at Brown University; Raquel D’Oyen ’90, who holds a PhD from Northwestern University and is a senior engineer at Raytheon; and Ashley Kaiser MS ’19, PhD ’21, senior process engineer at 6K.

Students also had an opportunity to share their work with each other through research presentations. Their presentations covered a wide range of topics, including: developing a computer program to calculate solubility parameters for polymers used in textile manufacturing; performing a life-cycle analysis of a photonic chip and evaluating its environmental impact in comparison to a standard silicon microchip; and applying machine learning algorithms to scanning transmission electron microscopy images of CrSBr, a two-dimensional magnetic material. 

“The summit was wonderful and the best academic experience I have had as a first-year college student,” says MICRO intern Gabriella La Cour, who is pursuing a major in chemistry and dual degree biomedical engineering at Spelman College and participates in MICRO through MIT. “I got to meet so many students who were all in grades above me … and I learned a little about how to navigate college as an upperclassman.” 

“I actually have an extremely close friendship with one of the students, and we keep in touch regularly,” adds La Cour. “Professor Chazot gave valuable advice about applications and recommendation letters that will be useful when I apply to REUs [Research Experiences for Undergraduates] and graduate schools.”

Looking to the future, MICRO organizers hope to continue to grow the program’s reach.

“We would love to see other schools taking on this model,” says Sandland. “There are a lot of opportunities out there. The more departments, research groups, and mentors that get involved with this program, the more impact it can have.”

© Photo courtesy of the DMSE

Ten undergraduates from 10 universities around the United States visited MIT to participate in the first MICRO Summit earlier this year. Pictured are the student interns, organizers, and the career panelists.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.

Fostering research, careers, and community in materials science

Gabrielle Wood, a junior at Howard University majoring in chemical engineering, is on a mission to improve the sustainability and life cycles of natural resources and materials. Her work in the Materials Initiative for Comprehensive Research Opportunity (MICRO) program has given her hands-on experience with many different aspects of research, including MATLAB programming, experimental design, data analysis, figure-making, and scientific writing.

Wood is also one of 10 undergraduates from 10 universities around the United States to participate in the first MICRO Summit earlier this year. The internship program, developed by the MIT Department of Materials Science and Engineering (DMSE), first launched in fall 2021. Now in its third year, the program continues to grow, providing even more opportunities for non-MIT undergraduate students — including the MICRO Summit and the program’s expansion to include Northwestern University.

“I think one of the most valuable aspects of the MICRO program is the ability to do research long term with an experienced professor in materials science and engineering,” says Wood. “My school has limited opportunities for undergraduate research in sustainable polymers, so the MICRO program allowed me to gain valuable experience in this field, which I would not otherwise have.”

Like Wood, Griheydi Garcia, a senior chemistry major at Manhattan College, values the exposure to materials science, especially since she is not able to learn as much about it at her home institution.

“I learned a lot about crystallography and defects in materials through the MICRO curriculum, especially through videos,” says Garcia. “The research itself is very valuable, as well, because we get to apply what we’ve learned through the videos in the research we do remotely.”

Expanding research opportunities

From the beginning, the MICRO program was designed as a fully remote, rigorous education and mentoring program targeted toward students from underserved backgrounds interested in pursuing graduate school in materials science or related fields. Interns are matched with faculty to work on their specific research interests.

Jessica Sandland ’99, PhD ’05, principal lecturer in DMSE and co-founder of MICRO, says that research projects for the interns are designed to be work that they can do remotely, such as developing a machine-learning algorithm or a data analysis approach.

“It’s important to note that it’s not just about what the program and faculty are bringing to the student interns,” says Sandland, a member of the MIT Digital Learning Lab, a joint program between MIT Open Learning and the Institute’s academic departments. “The students are doing real research and work, and creating things of real value. It’s very much an exchange.”

Cécile Chazot PhD ’22, now an assistant professor of materials science and engineering at Northwestern University, had helped to establish MICRO at MIT from the very beginning. Once at Northwestern, she quickly realized that expanding MICRO to Northwestern would offer even more research opportunities to interns than by relying on MIT alone — leveraging the university’s strong materials science and engineering department, as well as offering resources for biomaterials research through Northwestern’s medical school. The program received funding from 3M and officially launched at Northwestern in fall 2023. Approximately half of the MICRO interns are now in the program with MIT and half are with Northwestern. Wood and Garcia both participate in the program via Northwestern.

“By expanding to another school, we’ve been able to have interns work with a much broader range of research projects,” says Chazot. “It has become easier for us to place students with faculty and research that match their interests.”

Building community

The MICRO program received a Higher Education Innovation grant from the Abdul Latif Jameel World Education Lab, part of MIT Open Learning, to develop an in-person summit. In January 2024, interns visited MIT for three days of presentations, workshops, and campus tours — including a tour of the MIT.nano building — as well as various community-building activities.

“A big part of MICRO is the community,” says Chazot. “A highlight of the summit was just seeing the students come together.”

The summit also included panel discussions that allowed interns to gain insights and advice from graduate students and professionals. The graduate panel discussion included MIT graduate students Sam Figueroa (mechanical engineering), Isabella Caruso (DMSE), and Eliana Feygin (DMSE). The career panel was led by Chazot and included Jatin Patil PhD ’23, head of product at SiTration; Maureen Reitman ’90, ScD ’93, group vice president and principal engineer at Exponent; Lucas Caretta PhD ’19, assistant professor of engineering at Brown University; Raquel D’Oyen ’90, who holds a PhD from Northwestern University and is a senior engineer at Raytheon; and Ashley Kaiser MS ’19, PhD ’21, senior process engineer at 6K.

Students also had an opportunity to share their work with each other through research presentations. Their presentations covered a wide range of topics, including: developing a computer program to calculate solubility parameters for polymers used in textile manufacturing; performing a life-cycle analysis of a photonic chip and evaluating its environmental impact in comparison to a standard silicon microchip; and applying machine learning algorithms to scanning transmission electron microscopy images of CrSBr, a two-dimensional magnetic material. 

“The summit was wonderful and the best academic experience I have had as a first-year college student,” says MICRO intern Gabriella La Cour, who is pursuing a major in chemistry and dual degree biomedical engineering at Spelman College and participates in MICRO through MIT. “I got to meet so many students who were all in grades above me … and I learned a little about how to navigate college as an upperclassman.” 

“I actually have an extremely close friendship with one of the students, and we keep in touch regularly,” adds La Cour. “Professor Chazot gave valuable advice about applications and recommendation letters that will be useful when I apply to REUs [Research Experiences for Undergraduates] and graduate schools.”

Looking to the future, MICRO organizers hope to continue to grow the program’s reach.

“We would love to see other schools taking on this model,” says Sandland. “There are a lot of opportunities out there. The more departments, research groups, and mentors that get involved with this program, the more impact it can have.”

© Photo courtesy of the DMSE

Ten undergraduates from 10 universities around the United States visited MIT to participate in the first MICRO Summit earlier this year. Pictured are the student interns, organizers, and the career panelists.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.

A first-ever complete map for elastic strain engineering

Without a map, it can be just about impossible to know not just where you are, but where you’re going, and that’s especially true when it comes to materials properties.

For decades, scientists have understood that while bulk materials behave in certain ways, those rules can break down for materials at the micro- and nano-scales, and often in surprising ways. One of those surprises was the finding that, for some materials, applying even modest strains — a concept known as elastic strain engineering — on materials can dramatically improve certain properties, provided those strains stay elastic and do not relax away by plasticity, fracture, or phase transformations. Micro- and nano-scale materials are especially good at holding applied strains in the elastic form.

Precisely how to apply those elastic strains (or equivalently, residual stress) to achieve certain material properties, however, had been less clear — until recently.

Using a combination of first principles calculations and machine learning, a team of MIT researchers has developed the first-ever map of how to tune crystalline materials to produce specific thermal and electronic properties.

Led by Ju Li, the Battelle Energy Alliance Professor in Nuclear Engineering and professor of materials science and engineering, the team described a framework for understanding precisely how changing the elastic strains on a material can fine-tune properties like thermal and electrical conductivity. The work is described in an open-access paper published in PNAS.

“For the first time, by using machine learning, we’ve been able to delineate the complete six-dimensional boundary of ideal strength, which is the upper limit to elastic strain engineering, and create a map for these electronic and phononic properties,” Li says. “We can now use this approach to explore many other materials. Traditionally, people create new materials by changing the chemistry.”

“For example, with a ternary alloy, you can change the percentage of two elements, so you have two degrees of freedom,” he continues. “What we’ve shown is that diamond, with just one element, is equivalent to a six-component alloy, because you have six degrees of elastic strain freedom you can tune independently.”

Small strains, big material benefits

The paper builds on a foundation laid as far back as the 1980s, when researchers first discovered that the performance of semiconductor materials doubled when a small — just 1 percent — elastic strain was applied to the material.

While that discovery was quickly commercialized by the semiconductor industry and today is used to increase the performance of microchips in everything from laptops to cellphones, that level of strain is very small compared to what we can achieve now, says Subra Suresh, the Vannevar Bush Professor of Engineering Emeritus.

In a 2018 Science paper, Suresh, Dao, and colleagues demonstrated that 1 percent strain was just the tip of the iceberg.

As part of a 2018 study, Suresh and colleagues demonstrated for the first time that diamond nanoneedles could withstand elastic strains of as much as 9 percent and still return to their original state. Later on, several groups independently confirmed that microscale diamond can indeed elastically deform by approximately 7 percent in tension reversibly.

“Once we showed we could bend nanoscale diamonds and create strains on the order of 9 or 10 percent, the question was, what do you do with it,” Suresh says. “It turns out diamond is a very good semiconductor material … and one of our questions was, if we can mechanically strain diamond, can we reduce the band gap from 5.6 electron-volts to two or three? Or can we get it all the way down to zero, where it begins to conduct like a metal?”

To answer those questions, the team first turned to machine learning in an effort to get a more precise picture of exactly how strain altered material properties.

“Strain is a big space,” Li explains. “You can have tensile strain, you can have shear strain in multiple directions, so it’s a six-dimensional space, and the phonon band is three-dimensional, so in total there are nine tunable parameters. So, we’re using machine learning, for the first time, to create a complete map for navigating the electronic and phononic properties and identify the boundaries.”

Armed with that map, the team subsequently demonstrated how strain could be used to dramatically alter diamond’s semiconductor properties.

“Diamond is like the Mt. Everest of electronic materials,” Li says, “because it has very high thermal conductivity, very high dielectric breakdown strengths, a very big carrier mobility. What we have shown is we can controllably squish Mt. Everest down … so we show that by strain engineering you can either improve diamond’s thermal conductivity by a factor of two, or make it much worse by a factor of 20.”

New map, new applications

Going forward, the findings could be used to explore a host of exotic material properties, Li says, from dramatically reduced thermal conductivity to superconductivity.

“Experimentally, these properties are already accessible with nanoneedles and even microbridges,” he says. “And we have seen exotic properties, like reducing diamond’s (thermal conductivity) to only a few hundred watts per meter-Kelvin. Recently, people have shown that you can produce room-temperature superconductors with hydrides if you squeeze them to a few hundred gigapascals, so we have found all kinds of exotic behavior once we have the map.”

The results could also influence the design of next-generation computer chips capable of running much faster and cooler than today’s processors, as well as quantum sensors and communication devices. As the semiconductor manufacturing industry moves to denser and denser architectures, Suresh says the ability to tune a material’s thermal conductivity will be particularly important for heat dissipation.

While the paper could inform the design of future generations of microchips, Zhe Shi, a postdoc in Li’s lab and first author of the paper, says more work will be needed before those chips find their way into the average laptop or cellphone.

“We know that 1 percent strain can give you an order of magnitude increase in the clock speed of your CPU,” Shi says. “There are a lot of manufacturing and device problems that need to be solved in order for this to become realistic, but I think it’s definitely a great start. It’s an exciting beginning to what could lead to significant strides in technology.”

This work was supported with funding from the Defense Threat Reduction Agency, an NSF Graduate Research Fellowship, the Nanyang Technological University School of Biological Sciences, the National Science Foundation (NSF), the MIT Vannevar Bush Professorship, and a Nanyang Technological University Distinguished University Professorship.

© Image courtesy of the researchers.

The “map,” or the phonon stability boundary, is a graphical representation that plots the stability regions of a crystal as a function of strain. This map helps scientists and engineers determine the conditions under which a material can exist in a particular phase and when it might fail or transition to another phase. By analyzing the phonon stability boundary, researchers can understand material properties at extreme conditions and design new materials with desired characteristics.
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