A Barcelona-based startup called Inbrain Neuroelectronics has produced a novel brain implant made of graphene and is gearing up for its first in-human test this summer.

The technology is a type of brain-computer interface. BCIs have garnered interest because they record signals from the brain and transmit them to a computer for analysis. They have been used for medical diagnostics, as communication devices for people who can’t speak, and to control external equipment, including robotic limbs. But Inbrain intends to transform its BCI technology into a therapeutic tool for patients with neurological issues such as Parkinson’s disease.

Because Inbrain’s chip is made of graphene, the neural interface has some interesting properties, including the ability to be used to both record from and stimulate the brain. That bidirectionality comes from addressing a key problem with the metallic chips typically used in BCI technology: Faradaic reactions. Faradaic reactions are a particular type of electrochemical processes that occurs between a metal electrode and an electrolyte solution. As it so happens, neural tissue is largely composed of aqueous electrolytes. Over time, these Faradaic reactions reduce the effectiveness of the metallic chips.

That’s why Inbrain replaced the metals typically used in such chips with graphene, a material with great electrical conductivity. “Metals have Faraday reactions that actually make all the electrons interact with each other, degrading their effectiveness...for transmitting signals back to the brain,” said Carolina Aguilar, CEO and cofounder of Inbrain.

Because graphene is essentially carbon and not a metal, Aguilar says the chip can inject 200 times as much charge without creating a Faradic reaction. As a result, the material is stable over the millions of pulses of stimulation required of a therapeutic tool. While Inbrain is not yet testing the chip for brain stimulation, the company expects to reach that goal in due time.

The graphene-based chip is produced on a wafer using traditional semiconductor technology, according to Aguilar. At clean-room facilities, Inbrain fabricates a 10-micrometer-thick chip. The chip consists of what Aguilar terms “graphene dots” (not to be confused with graphene quantum dots) that range in size from 25 to 300 micrometers. “This micrometer scale allows us to get that unique resolution on the decoding of the signals from the brain, and also provides us with the micrometric stimulation or modulation of the brain,” added Aguilar.

Testing the Graphene-Based BCI

The first test of the platform in a human patient will soon be performed at the University of Manchester, in England, where it will serve as an interface during the resection of a brain tumor. When resecting a tumor, surgeons must ensure that they don’t damage areas like the brain’s language centers so the patient isn’t impaired after the surgery. “The chip is positioned during the tumor resection so that it can read, at a very high resolution, the signals that tell the surgeon where there is a tumor and where there is not a tumor,” says Aguilar. That should enable the surgeons to extract the tumor with micrometric precision while preserving functional areas like speech and cognition.

Aguilar added, “We have taken this approach for our first human test because it is a very reliable and quick path to prove the safety of graphene, but also demonstrate the potential of what it can do in comparison to metal technology that is used today.”

Aguilar stresses that the Inbrain team has already tested the graphene-based chip’s biocompatibility. “We have been working for the last three years in biocompatibility through various safety studies in large animals,” said Aguilar. “So now we can have these green lights to prove an additional level of safety with humans.”

While this test of the chip at Manchester is aimed at aiding in brain tumor surgery, the same technology could eventually be used to help Parkinson’s patients. Toward this aim, Inbrain’s system was granted Breakthrough Device Designation last September from the U.S. Food & Drug Administration as an adjunctive therapy for treating Parkinson’s disease. “For Parkinson’s treatment, we have been working on different preclinical studies that have shown reasonable proof of superiority versus current commercial technology in the [reduction] of Parkinson’s disease symptoms,” said Aguilar.

For treating Parkinson’s, Inbrain’s chip connects with the nigrostriatal pathway in the brain that is critical for movements. The chip will first decode the intention message from the brain that triggers a step or the lifting of the arm—something that a typical BCI can do. But Inbrain’s chip, with its micrometric precision, can also decode pathological biomarkers related to Parkinson’s symptoms, such as tremors, rigidity, and freezing of the gait.

By determining these biomarkers with great precision, Inbrain’s technology can determine how well a patient’s current drug regimen is working. In this first iteration of the Inbrain chip, it doesn’t treat the symptoms of Parkinson’s directly, but instead makes it possible to better target and reduce the amount of drugs that are used in treatment.

“Parkinson’s patients take huge amounts of drugs that have to be changed over time just to keep up with the growing resistance patients develop to the power of the drug,” said Aguilar. “We can reduce it at least 50 percent and hopefully in the future more as our devices become precise.”

MIT physicists and colleagues have created a five-lane superhighway for electrons that could allow ultra-efficient electronics and more. 

The work, reported in the May 10 issue of Science, is one of several important discoveries by the same team over the past year involving a material that is a unique form of graphene.

“This discovery has direct implications for low-power electronic devices because no energy is lost during the propagation of electrons, which is not the case in regular materials where the electrons are scattered,” says Long Ju, an assistant professor in the Department of Physics and corresponding author of the Science paper.

The phenomenon is akin to cars traveling down an open turnpike as opposed to those moving through neighborhoods. The neighborhood cars can be stopped or slowed by other drivers making abrupt stops or U-turns that disrupt an otherwise smooth commute.

A new material

The material behind this work, known as rhombohedral pentalayer graphene, was discovered two years ago by physicists led by Ju. “We found a goldmine, and every scoop is revealing something new,” says Ju, who is also affiliated with MIT’s Materials Research Laboratory.

In a Nature Nanotechnology paper last October, Ju and colleagues reported the discovery of three important properties arising from rhombohedral graphene. For example, they showed that it could be topological, or allow the unimpeded movement of electrons around the edge of the material but not through the middle. That resulted in a superhighway, but required the application of a large magnetic field some tens of thousands times stronger than the Earth’s magnetic field.

In the current work, the team reports creating the superhighway without any magnetic field.

Tonghang Han, an MIT graduate student in physics, is a co-first author of the paper. “We are not the first to discover this general phenomenon, but we did so in a very different system. And compared to previous systems, ours is simpler and also supports more electron channels.” Explains Ju, “other materials can only support one lane of traffic on the edge of the material. We suddenly bumped it up to five.”

Additional co-first authors of the paper who contributed equally to the work are Zhengguang Lu and Yuxuan Yao. Lu is a postdoc in the Materials Research Laboratory. Yao conducted the work as a visiting undergraduate student from Tsinghua University. Other authors are MIT professor of physics Liang Fu; Jixiang Yang and Junseok Seo, both MIT graduate students in physics; Chiho Yoon and Fan Zhang of the University of Texas at Dallas; and Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan.

How it works

Graphite, the primary component of pencil lead, is composed of many layers of graphene, a single layer of carbon atoms arranged in hexagons resembling a honeycomb structure. Rhombohedral graphene is composed of five layers of graphene stacked in a specific overlapping order.

Ju and colleagues isolated rhombohedral graphene thanks to a novel microscope Ju built at MIT in 2021 that can quickly and relatively inexpensively determine a variety of important characteristics of a material at the nanoscale. Pentalayer rhombohedral stacked graphene is only a few billionths of a meter thick.

In the current work, the team tinkered with the original system, adding a layer of tungsten disulfide (WS₂). “The interaction between the WS₂ and the pentalayer rhombohedral graphene resulted in this five-lane superhighway that operates at zero magnetic field,” says Ju.

Comparison to superconductivity

The phenomenon that the Ju group discovered in rhombohedral graphene that allows electrons to travel with no resistance at zero magnetic field is known as the quantum anomalous Hall effect. Most people are more familiar with superconductivity, a completely different phenomenon that does the same thing but happens in very different materials.

Ju notes that although superconductors were discovered in the 1910s, it took some 100 years of research to coax the system to work at the higher temperatures necessary for applications. “And the world record is still well below room temperature,” he notes.

Similarly, the rhombohedral graphene superhighway currently operates at about 2 kelvins, or -456 degrees Fahrenheit. “It will take a lot of effort to elevate the temperature, but as physicists, our job is to provide the insight; a different way for realizing this [phenomenon],” Ju says.

Very exciting

The discoveries involving rhombohedral graphene came as a result of painstaking research that wasn’t guaranteed to work. “We tried many recipes over many months,” says Han, “so it was very exciting when we cooled the system to a very low temperature and [a five-lane superhighway operating at zero magnetic field] just popped out.”

Says Ju, “it’s very exciting to be the first to discover a phenomenon in a new system, especially in a material that we uncovered.”

This work was supported by a Sloan Fellowship; the U.S. National Science Foundation; the U.S. Office of the Under Secretary of Defense for Research and Engineering; the Japan Society for the Promotion of Science KAKENHI; and the World Premier International Research Initiative of Japan.

Physics graduate student Jeong Min (Jane) Park is among the 32 exceptional early-career scientists worldwide chosen to receive the prestigious 2024 Schmidt Science Fellows award.  

As a 2024 Schmidt Science Fellow, Park’s postdoctoral work will seek to directly detect phases that could host new particles by employing an instrument that can visualize subatomic-scale phenomena.  

With her advisor, Pablo Jarillo-Herrero, the Cecil and Ida Green Professor of Physics, Park’s research at MIT focuses on discovering novel quantum phases of matter.

“When there are many electrons in a material, their interactions can lead to collective behaviors that are not expected from individual particles, known as emergent phenomena,” explains Park. “One example is superconductivity, where interacting electrons combine together as a pair at low temperatures to conduct electricity without energy loss.”

During her PhD studies, she has investigated novel types of superconductivity by designing new materials with targeted interactions and topology. In particular, she used graphene, atomically thin two-dimensional layers of graphite, the same material as pencil lead, and turned it into a “magic” material. This so-called magic-angle twisted trilayer graphene provided an extraordinarily strong form of superconductivity that is robust under high magnetic fields. Later, she found a whole “magic family” of these materials, elucidating the key mechanisms behind superconductivity and interaction-driven phenomena. These results have provided a new platform to study emergent phenomena in two dimensions, which can lead to innovations in electronics and quantum technology.

Park says she is looking forward to her postdoctoral studies with Princeton University physics professor Ali Yazdani's lab.

“I’m excited about the idea of discovering and studying new quantum phenomena that could further the understanding of fundamental physics,” says Park. “Having explored interaction-driven phenomena through the design of new materials, I’m now aiming to broaden my perspective and expertise to address a different kind of question, by combining my background in material design with the sophisticated local-scale measurements that I will adopt during my postdoc.”

She explains that elementary particles are classified as either bosons or fermions, with contrasting behaviors upon interchanging two identical particles, referred to as exchange statistics; bosons remain unchanged, while fermions acquire a minus sign in their quantum wavefunction.

Theories predict the existence of fundamentally different particles known as non-abelian anyons, whose wavefunctions braid upon particle exchange. Such a braiding process can be used to encode and store information, potentially opening the door to fault-tolerant quantum computing in the future.

Since 2018, this prestigious postdoctoral program has sought to break down silos among scientific fields to solve the world’s biggest challenges and support future leaders in STEM.

Schmidt Science Fellows, an initiative of Schmidt Sciences, delivered in partnership with the Rhodes Trust, identifies, develops, and amplifies the next generation of science leaders, by building a community of scientists and supporters of interdisciplinary science and leveraging this network to drive sector-wide change. The 2024 fellows consist of 17 nationalities across North America, Europe, and Asia.   

Nominated candidates undergo a rigorous selection process that includes a paper-based academic review with panels of experts in their home disciplines and final interviews with panels, including senior representatives from across many scientific disciplines and different business sectors.  

MIT physicists and colleagues have created a five-lane superhighway for electrons that could allow ultra-efficient electronics and more. 

The work, reported in the May 10 issue of Science, is one of several important discoveries by the same team over the past year involving a material that is a unique form of graphene.

“This discovery has direct implications for low-power electronic devices because no energy is lost during the propagation of electrons, which is not the case in regular materials where the electrons are scattered,” says Long Ju, an assistant professor in the Department of Physics and corresponding author of the Science paper.

The phenomenon is akin to cars traveling down an open turnpike as opposed to those moving through neighborhoods. The neighborhood cars can be stopped or slowed by other drivers making abrupt stops or U-turns that disrupt an otherwise smooth commute.

A new material

The material behind this work, known as rhombohedral pentalayer graphene, was discovered two years ago by physicists led by Ju. “We found a goldmine, and every scoop is revealing something new,” says Ju, who is also affiliated with MIT’s Materials Research Laboratory.

In a Nature Nanotechnology paper last October, Ju and colleagues reported the discovery of three important properties arising from rhombohedral graphene. For example, they showed that it could be topological, or allow the unimpeded movement of electrons around the edge of the material but not through the middle. That resulted in a superhighway, but required the application of a large magnetic field some tens of thousands times stronger than the Earth’s magnetic field.

In the current work, the team reports creating the superhighway without any magnetic field.

Tonghang Han, an MIT graduate student in physics, is a co-first author of the paper. “We are not the first to discover this general phenomenon, but we did so in a very different system. And compared to previous systems, ours is simpler and also supports more electron channels.” Explains Ju, “other materials can only support one lane of traffic on the edge of the material. We suddenly bumped it up to five.”

Additional co-first authors of the paper who contributed equally to the work are Zhengguang Lu and Yuxuan Yao. Lu is a postdoc in the Materials Research Laboratory. Yao conducted the work as a visiting undergraduate student from Tsinghua University. Other authors are MIT professor of physics Liang Fu; Jixiang Yang and Junseok Seo, both MIT graduate students in physics; Chiho Yoon and Fan Zhang of the University of Texas at Dallas; and Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan.

How it works

Graphite, the primary component of pencil lead, is composed of many layers of graphene, a single layer of carbon atoms arranged in hexagons resembling a honeycomb structure. Rhombohedral graphene is composed of five layers of graphene stacked in a specific overlapping order.

Ju and colleagues isolated rhombohedral graphene thanks to a novel microscope Ju built at MIT in 2021 that can quickly and relatively inexpensively determine a variety of important characteristics of a material at the nanoscale. Pentalayer rhombohedral stacked graphene is only a few billionths of a meter thick.

In the current work, the team tinkered with the original system, adding a layer of tungsten disulfide (WS₂). “The interaction between the WS₂ and the pentalayer rhombohedral graphene resulted in this five-lane superhighway that operates at zero magnetic field,” says Ju.

Comparison to superconductivity

The phenomenon that the Ju group discovered in rhombohedral graphene that allows electrons to travel with no resistance at zero magnetic field is known as the quantum anomalous Hall effect. Most people are more familiar with superconductivity, a completely different phenomenon that does the same thing but happens in very different materials.

Ju notes that although superconductors were discovered in the 1910s, it took some 100 years of research to coax the system to work at the higher temperatures necessary for applications. “And the world record is still well below room temperature,” he notes.

Similarly, the rhombohedral graphene superhighway currently operates at about 2 kelvins, or -456 degrees Fahrenheit. “It will take a lot of effort to elevate the temperature, but as physicists, our job is to provide the insight; a different way for realizing this [phenomenon],” Ju says.

Very exciting

The discoveries involving rhombohedral graphene came as a result of painstaking research that wasn’t guaranteed to work. “We tried many recipes over many months,” says Han, “so it was very exciting when we cooled the system to a very low temperature and [a five-lane superhighway operating at zero magnetic field] just popped out.”

Says Ju, “it’s very exciting to be the first to discover a phenomenon in a new system, especially in a material that we uncovered.”

This work was supported by a Sloan Fellowship; the U.S. National Science Foundation; the U.S. Office of the Under Secretary of Defense for Research and Engineering; the Japan Society for the Promotion of Science KAKENHI; and the World Premier International Research Initiative of Japan.

Physics graduate student Jeong Min (Jane) Park is among the 32 exceptional early-career scientists worldwide chosen to receive the prestigious 2024 Schmidt Science Fellows award.  

As a 2024 Schmidt Science Fellow, Park’s postdoctoral work will seek to directly detect phases that could host new particles by employing an instrument that can visualize subatomic-scale phenomena.  

With her advisor, Pablo Jarillo-Herrero, the Cecil and Ida Green Professor of Physics, Park’s research at MIT focuses on discovering novel quantum phases of matter.

“When there are many electrons in a material, their interactions can lead to collective behaviors that are not expected from individual particles, known as emergent phenomena,” explains Park. “One example is superconductivity, where interacting electrons combine together as a pair at low temperatures to conduct electricity without energy loss.”

During her PhD studies, she has investigated novel types of superconductivity by designing new materials with targeted interactions and topology. In particular, she used graphene, atomically thin two-dimensional layers of graphite, the same material as pencil lead, and turned it into a “magic” material. This so-called magic-angle twisted trilayer graphene provided an extraordinarily strong form of superconductivity that is robust under high magnetic fields. Later, she found a whole “magic family” of these materials, elucidating the key mechanisms behind superconductivity and interaction-driven phenomena. These results have provided a new platform to study emergent phenomena in two dimensions, which can lead to innovations in electronics and quantum technology.

Park says she is looking forward to her postdoctoral studies with Princeton University physics professor Ali Yazdani's lab.

“I’m excited about the idea of discovering and studying new quantum phenomena that could further the understanding of fundamental physics,” says Park. “Having explored interaction-driven phenomena through the design of new materials, I’m now aiming to broaden my perspective and expertise to address a different kind of question, by combining my background in material design with the sophisticated local-scale measurements that I will adopt during my postdoc.”

She explains that elementary particles are classified as either bosons or fermions, with contrasting behaviors upon interchanging two identical particles, referred to as exchange statistics; bosons remain unchanged, while fermions acquire a minus sign in their quantum wavefunction.

Theories predict the existence of fundamentally different particles known as non-abelian anyons, whose wavefunctions braid upon particle exchange. Such a braiding process can be used to encode and store information, potentially opening the door to fault-tolerant quantum computing in the future.

Since 2018, this prestigious postdoctoral program has sought to break down silos among scientific fields to solve the world’s biggest challenges and support future leaders in STEM.

Schmidt Science Fellows, an initiative of Schmidt Sciences, delivered in partnership with the Rhodes Trust, identifies, develops, and amplifies the next generation of science leaders, by building a community of scientists and supporters of interdisciplinary science and leveraging this network to drive sector-wide change. The 2024 fellows consist of 17 nationalities across North America, Europe, and Asia.   

Nominated candidates undergo a rigorous selection process that includes a paper-based academic review with panels of experts in their home disciplines and final interviews with panels, including senior representatives from across many scientific disciplines and different business sectors.  

Physics graduate student Jeong Min (Jane) Park is among the 32 exceptional early-career scientists worldwide chosen to receive the prestigious 2024 Schmidt Science Fellows award.  

As a 2024 Schmidt Science Fellow, Park’s postdoctoral work will seek to directly detect phases that could host new particles by employing an instrument that can visualize subatomic-scale phenomena.  

With her advisor, Pablo Jarillo-Herrero, the Cecil and Ida Green Professor of Physics, Park’s research at MIT focuses on discovering novel quantum phases of matter.

“When there are many electrons in a material, their interactions can lead to collective behaviors that are not expected from individual particles, known as emergent phenomena,” explains Park. “One example is superconductivity, where interacting electrons combine together as a pair at low temperatures to conduct electricity without energy loss.”

During her PhD studies, she has investigated novel types of superconductivity by designing new materials with targeted interactions and topology. In particular, she used graphene, atomically thin two-dimensional layers of graphite, the same material as pencil lead, and turned it into a “magic” material. This so-called magic-angle twisted trilayer graphene provided an extraordinarily strong form of superconductivity that is robust under high magnetic fields. Later, she found a whole “magic family” of these materials, elucidating the key mechanisms behind superconductivity and interaction-driven phenomena. These results have provided a new platform to study emergent phenomena in two dimensions, which can lead to innovations in electronics and quantum technology.

Park says she is looking forward to her postdoctoral studies with Princeton University physics professor Ali Yazdani's lab.

“I’m excited about the idea of discovering and studying new quantum phenomena that could further the understanding of fundamental physics,” says Park. “Having explored interaction-driven phenomena through the design of new materials, I’m now aiming to broaden my perspective and expertise to address a different kind of question, by combining my background in material design with the sophisticated local-scale measurements that I will adopt during my postdoc.”

She explains that elementary particles are classified as either bosons or fermions, with contrasting behaviors upon interchanging two identical particles, referred to as exchange statistics; bosons remain unchanged, while fermions acquire a minus sign in their quantum wavefunction.

Theories predict the existence of fundamentally different particles known as non-abelian anyons, whose wavefunctions braid upon particle exchange. Such a braiding process can be used to encode and store information, potentially opening the door to fault-tolerant quantum computing in the future.

Since 2018, this prestigious postdoctoral program has sought to break down silos among scientific fields to solve the world’s biggest challenges and support future leaders in STEM.

Schmidt Science Fellows, an initiative of Schmidt Sciences, delivered in partnership with the Rhodes Trust, identifies, develops, and amplifies the next generation of science leaders, by building a community of scientists and supporters of interdisciplinary science and leveraging this network to drive sector-wide change. The 2024 fellows consist of 17 nationalities across North America, Europe, and Asia.   

Nominated candidates undergo a rigorous selection process that includes a paper-based academic review with panels of experts in their home disciplines and final interviews with panels, including senior representatives from across many scientific disciplines and different business sectors.  

Physics graduate student Jeong Min (Jane) Park is among the 32 exceptional early-career scientists worldwide chosen to receive the prestigious 2024 Schmidt Science Fellows award.  

As a 2024 Schmidt Science Fellow, Park’s postdoctoral work will seek to directly detect phases that could host new particles by employing an instrument that can visualize subatomic-scale phenomena.  

With her advisor, Pablo Jarillo-Herrero, the Cecil and Ida Green Professor of Physics, Park’s research at MIT focuses on discovering novel quantum phases of matter.

“When there are many electrons in a material, their interactions can lead to collective behaviors that are not expected from individual particles, known as emergent phenomena,” explains Park. “One example is superconductivity, where interacting electrons combine together as a pair at low temperatures to conduct electricity without energy loss.”

During her PhD studies, she has investigated novel types of superconductivity by designing new materials with targeted interactions and topology. In particular, she used graphene, atomically thin two-dimensional layers of graphite, the same material as pencil lead, and turned it into a “magic” material. This so-called magic-angle twisted trilayer graphene provided an extraordinarily strong form of superconductivity that is robust under high magnetic fields. Later, she found a whole “magic family” of these materials, elucidating the key mechanisms behind superconductivity and interaction-driven phenomena. These results have provided a new platform to study emergent phenomena in two dimensions, which can lead to innovations in electronics and quantum technology.

Park says she is looking forward to her postdoctoral studies with Princeton University physics professor Ali Yazdani's lab.

“I’m excited about the idea of discovering and studying new quantum phenomena that could further the understanding of fundamental physics,” says Park. “Having explored interaction-driven phenomena through the design of new materials, I’m now aiming to broaden my perspective and expertise to address a different kind of question, by combining my background in material design with the sophisticated local-scale measurements that I will adopt during my postdoc.”

She explains that elementary particles are classified as either bosons or fermions, with contrasting behaviors upon interchanging two identical particles, referred to as exchange statistics; bosons remain unchanged, while fermions acquire a minus sign in their quantum wavefunction.

Theories predict the existence of fundamentally different particles known as non-abelian anyons, whose wavefunctions braid upon particle exchange. Such a braiding process can be used to encode and store information, potentially opening the door to fault-tolerant quantum computing in the future.

Since 2018, this prestigious postdoctoral program has sought to break down silos among scientific fields to solve the world’s biggest challenges and support future leaders in STEM.

Schmidt Science Fellows, an initiative of Schmidt Sciences, delivered in partnership with the Rhodes Trust, identifies, develops, and amplifies the next generation of science leaders, by building a community of scientists and supporters of interdisciplinary science and leveraging this network to drive sector-wide change. The 2024 fellows consist of 17 nationalities across North America, Europe, and Asia.   

Nominated candidates undergo a rigorous selection process that includes a paper-based academic review with panels of experts in their home disciplines and final interviews with panels, including senior representatives from across many scientific disciplines and different business sectors.  

MIT physicists have metaphorically turned graphite, or pencil lead, into gold by isolating five ultrathin flakes stacked in a specific order. The resulting material can then be tuned to exhibit three important properties never before seen in natural graphite.

“It is kind of like one-stop shopping,” says Long Ju, an assistant professor in the Department of Physics and leader of the work, which is reported in the Oct. 5 issue of Nature Nanotechnology. “Nature has plenty of surprises. In this case, we never realized that all of these interesting things are embedded in graphite.”

Further, he says, “It is very rare material to find materials that can host this many properties.”

Graphite is composed of graphene, which is a single layer of carbon atoms arranged in hexagons resembling a honeycomb structure. Graphene, in turn, has been the focus of intense research since it was first isolated about 20 years ago. More recently, about five years ago, researchers including a team at MIT discovered that stacking individual sheets of graphene, and twisting them at a slight angle to each other, can impart new properties to the material, from superconductivity to magnetism. The field of “twistronics” was born.

In the current work, “we discovered interesting properties with no twisting at all,” says Ju, who is also affiliated with the Materials Research Laboratory.

He and colleagues discovered that five layers of graphene arranged in a certain order allow the electrons moving around inside the material to talk with each other. That phenomenon, known as electron correlation, “is the magic that makes all of these new properties possible,” Ju says.

Bulk graphite — and even single sheets of graphene — are good electrical conductors, but that’s it. The material Ju and colleagues isolated, which they call pentalayer rhombohedral stacked graphene, becomes much more than the sum of its parts.

Novel microscope

Key to isolating the material was a novel microscope Ju built at MIT in 2021 that can quickly and relatively inexpensively determine a variety of important characteristics of a material at the nanoscale. Pentalayer rhombohedral stacked graphene is only a few billionths of a meter thick.

Scientists including Ju were looking for multilayer graphene that was stacked in a very precise order, known as rhombohedral stacking. Says Ju, “there are more than 10 possible stacking orders when you go to five layers. Rhombohedral is just one of them.” The microscope Ju built, known as Scattering-type Scanning Nearfield Optical Microscopy, or s-SNOM, allowed the scientists to identify and isolate only the pentalayers in the rhombohedral stacking order they were interested in.

Three in one

From there, the team attached electrodes to a tiny sandwich composed of boron nitride “bread” that protects the delicate “meat” of pentalayer rhombohedral stacked graphene. The electrodes allowed them to tune the system with different voltages, or amounts of electricity. The result: They discovered the emergence of three different phenomena depending on the number of electrons flooding the system.

“We found that the material could be insulating, magnetic, or topological,” Ju says. The latter is somewhat related to both conductors and insulators. Essentially, Ju explains, a topological material allows the unimpeded movement of electrons around the edges of a material, but not through the middle. The electrons are traveling in one direction along a “highway” at the edge of the material separated by a median that makes up the center of the material. So the edge of a topological material is a perfect conductor, while the center is an insulator.

“Our work establishes rhombohedral stacked multilayer graphene as a highly tunable platform to study these new possibilities of strongly correlated and topological physics,” Ju and his coauthors conclude in Nature Nanotechnology.

In addition to Ju, authors of the paper are Tonghang Han and Zhengguang Lu. Han is a graduate student in the Department of Physics; Lu is a postdoc in the Materials Research Laboratory. The two are co-first authors of the paper.

Other authors are Giovanni Scuri, Jiho Sung, Jue Wang and Hongkun Park of Harvard University; Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan; and Tianyi Han of the MIT Department of Physics.

This work was supported by a Sloan Fellowship; the U.S. National Science Foundation; the U.S. Office of the Under Secretary of Defense for Research and Engineering; the Japan Society for the Promotion of Science KAKENHI;  the World Premier International Research Initiative of Japan; and the U.S. Air Force Office of Scientific Research.

Ordinary pencil lead holds extraordinary properties when shaved down to layers as thin as an atom. A single, atom-thin sheet of graphite, known as graphene, is just a tiny fraction of the width of a human hair. Under a microscope, the material resembles a chicken-wire of carbon atoms linked in a hexagonal lattice.

Despite its waif-like proportions, scientists have found over the years that graphene is exceptionally strong. And when the material is stacked and twisted in specific contortions, it can take on surprising electronic behavior.

Now, MIT physicists have discovered another surprising property in graphene: When stacked in five layers, in a rhombohedral pattern, graphene takes on a very rare, “multiferroic” state, in which the material exhibits both unconventional magnetism and an exotic type of electronic behavior, which the team has coined ferro-valleytricity.

“Graphene is a fascinating material,” says team leader Long Ju, assistant professor of physics at MIT. “Every layer you add gives you essentially a new material. And now this is the first time we see ferro-valleytricity, and unconventional magnetism, in five layers of graphene. But we don’t see this property in one, two, three, or four layers.”

The discovery could help engineers design ultra-low-power, high-capacity data storage devices for classical and quantum computers.

“Having multiferroic properties in one material means that, if it could save energy and time to write a magnetic hard drive, you could also store double the amount of information compared to conventional devices,” Ju says.

His team reports their discovery today in Nature. MIT co-authors include lead author Tonghang Han, plus Zhengguang Lu, Tianyi Han, and Liang Fu; along with Harvard University collaborators Giovanni Scuri, Jiho Sung, Jue Wang, and Hongkun Park; and Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan.

A preference for order

A ferroic material is one that displays some coordinated behavior in its electric, magnetic, or structural properties. A magnet is a common example of a ferroic material: Its electrons can coordinate to spin in the same direction without an external magnetic field. As a result, the magnet points to a preferred direction in space, spontaneously.

Other materials can be ferroic through different means. But only a handful have been found to be multiferroic — a rare state in which multiple properties can coordinate to exhibit multiple preferred states. In conventional multiferroics, it would be as if, in addition to the magnet pointing toward one direction, the electric charge also shifts in a direction that is independent from the magnetic direction.  

Multiferroic materials are of interest for electronics because they could potentially increase the speed and lower the energy cost of hard drives. Magnetic hard drives store data in the form of magnetic domains — essentially, microscopic magnets that are read as either a 1 or a 0, depending on their magnetic orientation. The magnets are switched by an electric current, which consumes a lot of energy and cannot operate quickly. If a storage device could be made with multiferroic materials, the domains could be switched by a faster, much lower-power electric field. Ju and his colleagues were curious about whether multiferroic behavior would emerge in graphene. The material’s extremely thin structure is a unique environment in which researchers have discovered otherwise hidden, quantum interactions. In particular, Ju wondered whether graphene would display multiferroic, coordinated behavior among its electrons when arranged under certain conditions and configurations.

“We are looking for environments where electrons are slowed down — where their interactions with the surrounding lattice of atoms is small, so that their interactions with other electrons can come through,” Ju explains. “That’s when we have some chance of seeing interesting collective behaviors of electrons.”

The team carried out some simple calculations and found that some coordinated behavior among electrons should emerge in a structure of five graphene layers stacked together in a rhombohedral pattern. (Think of five chicken-wire fences, stacked and slightly shifted such that, viewed from the top, the structure would resemble a pattern of diamonds.)

“In five layers, electrons happen to be in a lattice environment where they move very slowly, so they can interact with other electrons effectively,” Ju says. “That’s when electron correlation effects start to dominate, and they can start to coordinate into certain preferred, ferroic orders.”

Magic flakes

The researchers then went into the lab to see whether they could actually observe multiferroic behavior in five-layer graphene. In their experiments, they started with a small block of graphite, from which they carefully exfoliated individual flakes. They used optical techniques to examine each flake, looking specifically for five-layer flakes, arranged naturally in a rhombohedral pattern.

“To some extent, nature does the magic,” said lead author and graduate student Han. “And we can look at all these flakes and tell which has five layers, in this rhombohedral stacking, which is what should give you this slowing-down effect in electrons.”

The team isolated several five-layer flakes and studied them at temperatures just above absolute zero. In such ultracold conditions, all other effects, such as thermally induced disorders within graphene, should be dampened, allowing interactions between electrons, to emerge. The researchers measured electrons’ response to an electric field and a magnetic field, and found that indeed, two ferroic orders, or sets of coordinated behaviors, emerged.

The first ferroic property was an unconventional magnetism: The electrons coordinated their orbital motion, like planets circling in the same direction. (In conventional magnets, electrons coordinate their “spin” — rotating in the same direction, while staying relatively fixed in space.)

The second ferroic property had to do with graphene’s electronic “valley.” In every conductive material, there are certain energy levels that electrons can occupy. A valley represents the lowest energy state that an electron can naturally settle. As it turns out, there are two possible valleys in graphene. Normally, electrons have no preference for either valley and settle equally into both.

But in five-layer graphene, the team found that the electrons began to coordinate, and preferred to settle in one valley over the other. This second coordinated behavior indicated a ferroic property that, combined with the electrons’ unconventional magnetism, gave the structure a rare, multiferroic state.

“We knew something interesting would happen in this structure, but we didn’t know exactly what, until we tested it,” says co-first author Lu, a postdoc in Ju’s group. “It’s the first time we’ve seen a ferro-valleytronics, and also the first time we’ve seen a coexistence of ferro-valleytronics with unconventional ferro-magnet.”

The team showed they could control both ferroic properties using an electric field. They envision that, if engineers can incorporate five-layer graphene or similar multiferroic materials into a memory chip, they could, in principle, use the same, low-power electric field to manipulate the material’s electrons in two ways rather than one, and effectively double the data that could be stored on a chip compared to conventional multiferroics. While that vision is far from practical realization, the team’s results break new ground in the search for better, more efficient electronic, magnetic and valleytronic devices.

This research was done, in part, using the electron-beam lithography facility run by MIT.nano, and is funded, in part, by the National Science Foundation and the Sloan Foundation.

MIT physicists have metaphorically turned graphite, or pencil lead, into gold by isolating five ultrathin flakes stacked in a specific order. The resulting material can then be tuned to exhibit three important properties never before seen in natural graphite.

“It is kind of like one-stop shopping,” says Long Ju, an assistant professor in the Department of Physics and leader of the work, which is reported in the Oct. 5 issue of Nature Nanotechnology. “Nature has plenty of surprises. In this case, we never realized that all of these interesting things are embedded in graphite.”

Further, he says, “It is very rare material to find materials that can host this many properties.”

Graphite is composed of graphene, which is a single layer of carbon atoms arranged in hexagons resembling a honeycomb structure. Graphene, in turn, has been the focus of intense research since it was first isolated about 20 years ago. More recently, about five years ago, researchers including a team at MIT discovered that stacking individual sheets of graphene, and twisting them at a slight angle to each other, can impart new properties to the material, from superconductivity to magnetism. The field of “twistronics” was born.

In the current work, “we discovered interesting properties with no twisting at all,” says Ju, who is also affiliated with the Materials Research Laboratory.

He and colleagues discovered that five layers of graphene arranged in a certain order allow the electrons moving around inside the material to talk with each other. That phenomenon, known as electron correlation, “is the magic that makes all of these new properties possible,” Ju says.

Bulk graphite — and even single sheets of graphene — are good electrical conductors, but that’s it. The material Ju and colleagues isolated, which they call pentalayer rhombohedral stacked graphene, becomes much more than the sum of its parts.

Novel microscope

Key to isolating the material was a novel microscope Ju built at MIT in 2021 that can quickly and relatively inexpensively determine a variety of important characteristics of a material at the nanoscale. Pentalayer rhombohedral stacked graphene is only a few billionths of a meter thick.

Scientists including Ju were looking for multilayer graphene that was stacked in a very precise order, known as rhombohedral stacking. Says Ju, “there are more than 10 possible stacking orders when you go to five layers. Rhombohedral is just one of them.” The microscope Ju built, known as Scattering-type Scanning Nearfield Optical Microscopy, or s-SNOM, allowed the scientists to identify and isolate only the pentalayers in the rhombohedral stacking order they were interested in.

Three in one

From there, the team attached electrodes to a tiny sandwich composed of boron nitride “bread” that protects the delicate “meat” of pentalayer rhombohedral stacked graphene. The electrodes allowed them to tune the system with different voltages, or amounts of electricity. The result: They discovered the emergence of three different phenomena depending on the number of electrons flooding the system.

“We found that the material could be insulating, magnetic, or topological,” Ju says. The latter is somewhat related to both conductors and insulators. Essentially, Ju explains, a topological material allows the unimpeded movement of electrons around the edges of a material, but not through the middle. The electrons are traveling in one direction along a “highway” at the edge of the material separated by a median that makes up the center of the material. So the edge of a topological material is a perfect conductor, while the center is an insulator.

“Our work establishes rhombohedral stacked multilayer graphene as a highly tunable platform to study these new possibilities of strongly correlated and topological physics,” Ju and his coauthors conclude in Nature Nanotechnology.

In addition to Ju, authors of the paper are Tonghang Han and Zhengguang Lu. Han is a graduate student in the Department of Physics; Lu is a postdoc in the Materials Research Laboratory. The two are co-first authors of the paper.

Other authors are Giovanni Scuri, Jiho Sung, Jue Wang and Hongkun Park of Harvard University; Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan; and Tianyi Han of the MIT Department of Physics.

This work was supported by a Sloan Fellowship; the U.S. National Science Foundation; the U.S. Office of the Under Secretary of Defense for Research and Engineering; the Japan Society for the Promotion of Science KAKENHI;  the World Premier International Research Initiative of Japan; and the U.S. Air Force Office of Scientific Research.

Ordinary pencil lead holds extraordinary properties when shaved down to layers as thin as an atom. A single, atom-thin sheet of graphite, known as graphene, is just a tiny fraction of the width of a human hair. Under a microscope, the material resembles a chicken-wire of carbon atoms linked in a hexagonal lattice.

Despite its waif-like proportions, scientists have found over the years that graphene is exceptionally strong. And when the material is stacked and twisted in specific contortions, it can take on surprising electronic behavior.

Now, MIT physicists have discovered another surprising property in graphene: When stacked in five layers, in a rhombohedral pattern, graphene takes on a very rare, “multiferroic” state, in which the material exhibits both unconventional magnetism and an exotic type of electronic behavior, which the team has coined ferro-valleytricity.

“Graphene is a fascinating material,” says team leader Long Ju, assistant professor of physics at MIT. “Every layer you add gives you essentially a new material. And now this is the first time we see ferro-valleytricity, and unconventional magnetism, in five layers of graphene. But we don’t see this property in one, two, three, or four layers.”

The discovery could help engineers design ultra-low-power, high-capacity data storage devices for classical and quantum computers.

“Having multiferroic properties in one material means that, if it could save energy and time to write a magnetic hard drive, you could also store double the amount of information compared to conventional devices,” Ju says.

His team reports their discovery today in Nature. MIT co-authors include lead author Tonghang Han, plus Zhengguang Lu, Tianyi Han, and Liang Fu; along with Harvard University collaborators Giovanni Scuri, Jiho Sung, Jue Wang, and Hongkun Park; and Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan.

A preference for order

A ferroic material is one that displays some coordinated behavior in its electric, magnetic, or structural properties. A magnet is a common example of a ferroic material: Its electrons can coordinate to spin in the same direction without an external magnetic field. As a result, the magnet points to a preferred direction in space, spontaneously.

Other materials can be ferroic through different means. But only a handful have been found to be multiferroic — a rare state in which multiple properties can coordinate to exhibit multiple preferred states. In conventional multiferroics, it would be as if, in addition to the magnet pointing toward one direction, the electric charge also shifts in a direction that is independent from the magnetic direction.  

Multiferroic materials are of interest for electronics because they could potentially increase the speed and lower the energy cost of hard drives. Magnetic hard drives store data in the form of magnetic domains — essentially, microscopic magnets that are read as either a 1 or a 0, depending on their magnetic orientation. The magnets are switched by an electric current, which consumes a lot of energy and cannot operate quickly. If a storage device could be made with multiferroic materials, the domains could be switched by a faster, much lower-power electric field. Ju and his colleagues were curious about whether multiferroic behavior would emerge in graphene. The material’s extremely thin structure is a unique environment in which researchers have discovered otherwise hidden, quantum interactions. In particular, Ju wondered whether graphene would display multiferroic, coordinated behavior among its electrons when arranged under certain conditions and configurations.

“We are looking for environments where electrons are slowed down — where their interactions with the surrounding lattice of atoms is small, so that their interactions with other electrons can come through,” Ju explains. “That’s when we have some chance of seeing interesting collective behaviors of electrons.”

The team carried out some simple calculations and found that some coordinated behavior among electrons should emerge in a structure of five graphene layers stacked together in a rhombohedral pattern. (Think of five chicken-wire fences, stacked and slightly shifted such that, viewed from the top, the structure would resemble a pattern of diamonds.)

“In five layers, electrons happen to be in a lattice environment where they move very slowly, so they can interact with other electrons effectively,” Ju says. “That’s when electron correlation effects start to dominate, and they can start to coordinate into certain preferred, ferroic orders.”

Magic flakes

The researchers then went into the lab to see whether they could actually observe multiferroic behavior in five-layer graphene. In their experiments, they started with a small block of graphite, from which they carefully exfoliated individual flakes. They used optical techniques to examine each flake, looking specifically for five-layer flakes, arranged naturally in a rhombohedral pattern.

“To some extent, nature does the magic,” said lead author and graduate student Han. “And we can look at all these flakes and tell which has five layers, in this rhombohedral stacking, which is what should give you this slowing-down effect in electrons.”

The team isolated several five-layer flakes and studied them at temperatures just above absolute zero. In such ultracold conditions, all other effects, such as thermally induced disorders within graphene, should be dampened, allowing interactions between electrons, to emerge. The researchers measured electrons’ response to an electric field and a magnetic field, and found that indeed, two ferroic orders, or sets of coordinated behaviors, emerged.

The first ferroic property was an unconventional magnetism: The electrons coordinated their orbital motion, like planets circling in the same direction. (In conventional magnets, electrons coordinate their “spin” — rotating in the same direction, while staying relatively fixed in space.)

The second ferroic property had to do with graphene’s electronic “valley.” In every conductive material, there are certain energy levels that electrons can occupy. A valley represents the lowest energy state that an electron can naturally settle. As it turns out, there are two possible valleys in graphene. Normally, electrons have no preference for either valley and settle equally into both.

But in five-layer graphene, the team found that the electrons began to coordinate, and preferred to settle in one valley over the other. This second coordinated behavior indicated a ferroic property that, combined with the electrons’ unconventional magnetism, gave the structure a rare, multiferroic state.

“We knew something interesting would happen in this structure, but we didn’t know exactly what, until we tested it,” says co-first author Lu, a postdoc in Ju’s group. “It’s the first time we’ve seen a ferro-valleytronics, and also the first time we’ve seen a coexistence of ferro-valleytronics with unconventional ferro-magnet.”

The team showed they could control both ferroic properties using an electric field. They envision that, if engineers can incorporate five-layer graphene or similar multiferroic materials into a memory chip, they could, in principle, use the same, low-power electric field to manipulate the material’s electrons in two ways rather than one, and effectively double the data that could be stored on a chip compared to conventional multiferroics. While that vision is far from practical realization, the team’s results break new ground in the search for better, more efficient electronic, magnetic and valleytronic devices.

This research was done, in part, using the electron-beam lithography facility run by MIT.nano, and is funded, in part, by the National Science Foundation and the Sloan Foundation.

MIT physicists have metaphorically turned graphite, or pencil lead, into gold by isolating five ultrathin flakes stacked in a specific order. The resulting material can then be tuned to exhibit three important properties never before seen in natural graphite.

“It is kind of like one-stop shopping,” says Long Ju, an assistant professor in the Department of Physics and leader of the work, which is reported in the Oct. 5 issue of Nature Nanotechnology. “Nature has plenty of surprises. In this case, we never realized that all of these interesting things are embedded in graphite.”

Further, he says, “It is very rare material to find materials that can host this many properties.”

Graphite is composed of graphene, which is a single layer of carbon atoms arranged in hexagons resembling a honeycomb structure. Graphene, in turn, has been the focus of intense research since it was first isolated about 20 years ago. More recently, about five years ago, researchers including a team at MIT discovered that stacking individual sheets of graphene, and twisting them at a slight angle to each other, can impart new properties to the material, from superconductivity to magnetism. The field of “twistronics” was born.

In the current work, “we discovered interesting properties with no twisting at all,” says Ju, who is also affiliated with the Materials Research Laboratory.

He and colleagues discovered that five layers of graphene arranged in a certain order allow the electrons moving around inside the material to talk with each other. That phenomenon, known as electron correlation, “is the magic that makes all of these new properties possible,” Ju says.

Bulk graphite — and even single sheets of graphene — are good electrical conductors, but that’s it. The material Ju and colleagues isolated, which they call pentalayer rhombohedral stacked graphene, becomes much more than the sum of its parts.

Novel microscope

Key to isolating the material was a novel microscope Ju built at MIT in 2021 that can quickly and relatively inexpensively determine a variety of important characteristics of a material at the nanoscale. Pentalayer rhombohedral stacked graphene is only a few billionths of a meter thick.

Scientists including Ju were looking for multilayer graphene that was stacked in a very precise order, known as rhombohedral stacking. Says Ju, “there are more than 10 possible stacking orders when you go to five layers. Rhombohedral is just one of them.” The microscope Ju built, known as Scattering-type Scanning Nearfield Optical Microscopy, or s-SNOM, allowed the scientists to identify and isolate only the pentalayers in the rhombohedral stacking order they were interested in.

Three in one

From there, the team attached electrodes to a tiny sandwich composed of boron nitride “bread” that protects the delicate “meat” of pentalayer rhombohedral stacked graphene. The electrodes allowed them to tune the system with different voltages, or amounts of electricity. The result: They discovered the emergence of three different phenomena depending on the number of electrons flooding the system.

“We found that the material could be insulating, magnetic, or topological,” Ju says. The latter is somewhat related to both conductors and insulators. Essentially, Ju explains, a topological material allows the unimpeded movement of electrons around the edges of a material, but not through the middle. The electrons are traveling in one direction along a “highway” at the edge of the material separated by a median that makes up the center of the material. So the edge of a topological material is a perfect conductor, while the center is an insulator.

“Our work establishes rhombohedral stacked multilayer graphene as a highly tunable platform to study these new possibilities of strongly correlated and topological physics,” Ju and his coauthors conclude in Nature Nanotechnology.

In addition to Ju, authors of the paper are Tonghang Han and Zhengguang Lu. Han is a graduate student in the Department of Physics; Lu is a postdoc in the Materials Research Laboratory. The two are co-first authors of the paper.

Other authors are Giovanni Scuri, Jiho Sung, Jue Wang and Hongkun Park of Harvard University; Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan; and Tianyi Han of the MIT Department of Physics.

This work was supported by a Sloan Fellowship; the U.S. National Science Foundation; the U.S. Office of the Under Secretary of Defense for Research and Engineering; the Japan Society for the Promotion of Science KAKENHI;  the World Premier International Research Initiative of Japan; and the U.S. Air Force Office of Scientific Research.

Ordinary pencil lead holds extraordinary properties when shaved down to layers as thin as an atom. A single, atom-thin sheet of graphite, known as graphene, is just a tiny fraction of the width of a human hair. Under a microscope, the material resembles a chicken-wire of carbon atoms linked in a hexagonal lattice.

Despite its waif-like proportions, scientists have found over the years that graphene is exceptionally strong. And when the material is stacked and twisted in specific contortions, it can take on surprising electronic behavior.

Now, MIT physicists have discovered another surprising property in graphene: When stacked in five layers, in a rhombohedral pattern, graphene takes on a very rare, “multiferroic” state, in which the material exhibits both unconventional magnetism and an exotic type of electronic behavior, which the team has coined ferro-valleytricity.

“Graphene is a fascinating material,” says team leader Long Ju, assistant professor of physics at MIT. “Every layer you add gives you essentially a new material. And now this is the first time we see ferro-valleytricity, and unconventional magnetism, in five layers of graphene. But we don’t see this property in one, two, three, or four layers.”

The discovery could help engineers design ultra-low-power, high-capacity data storage devices for classical and quantum computers.

“Having multiferroic properties in one material means that, if it could save energy and time to write a magnetic hard drive, you could also store double the amount of information compared to conventional devices,” Ju says.

His team reports their discovery today in Nature. MIT co-authors include lead author Tonghang Han, plus Zhengguang Lu, Tianyi Han, and Liang Fu; along with Harvard University collaborators Giovanni Scuri, Jiho Sung, Jue Wang, and Hongkun Park; and Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan.

A preference for order

A ferroic material is one that displays some coordinated behavior in its electric, magnetic, or structural properties. A magnet is a common example of a ferroic material: Its electrons can coordinate to spin in the same direction without an external magnetic field. As a result, the magnet points to a preferred direction in space, spontaneously.

Other materials can be ferroic through different means. But only a handful have been found to be multiferroic — a rare state in which multiple properties can coordinate to exhibit multiple preferred states. In conventional multiferroics, it would be as if, in addition to the magnet pointing toward one direction, the electric charge also shifts in a direction that is independent from the magnetic direction.  

Multiferroic materials are of interest for electronics because they could potentially increase the speed and lower the energy cost of hard drives. Magnetic hard drives store data in the form of magnetic domains — essentially, microscopic magnets that are read as either a 1 or a 0, depending on their magnetic orientation. The magnets are switched by an electric current, which consumes a lot of energy and cannot operate quickly. If a storage device could be made with multiferroic materials, the domains could be switched by a faster, much lower-power electric field. Ju and his colleagues were curious about whether multiferroic behavior would emerge in graphene. The material’s extremely thin structure is a unique environment in which researchers have discovered otherwise hidden, quantum interactions. In particular, Ju wondered whether graphene would display multiferroic, coordinated behavior among its electrons when arranged under certain conditions and configurations.

“We are looking for environments where electrons are slowed down — where their interactions with the surrounding lattice of atoms is small, so that their interactions with other electrons can come through,” Ju explains. “That’s when we have some chance of seeing interesting collective behaviors of electrons.”

The team carried out some simple calculations and found that some coordinated behavior among electrons should emerge in a structure of five graphene layers stacked together in a rhombohedral pattern. (Think of five chicken-wire fences, stacked and slightly shifted such that, viewed from the top, the structure would resemble a pattern of diamonds.)

“In five layers, electrons happen to be in a lattice environment where they move very slowly, so they can interact with other electrons effectively,” Ju says. “That’s when electron correlation effects start to dominate, and they can start to coordinate into certain preferred, ferroic orders.”

Magic flakes

The researchers then went into the lab to see whether they could actually observe multiferroic behavior in five-layer graphene. In their experiments, they started with a small block of graphite, from which they carefully exfoliated individual flakes. They used optical techniques to examine each flake, looking specifically for five-layer flakes, arranged naturally in a rhombohedral pattern.

“To some extent, nature does the magic,” said lead author and graduate student Han. “And we can look at all these flakes and tell which has five layers, in this rhombohedral stacking, which is what should give you this slowing-down effect in electrons.”

The team isolated several five-layer flakes and studied them at temperatures just above absolute zero. In such ultracold conditions, all other effects, such as thermally induced disorders within graphene, should be dampened, allowing interactions between electrons, to emerge. The researchers measured electrons’ response to an electric field and a magnetic field, and found that indeed, two ferroic orders, or sets of coordinated behaviors, emerged.

The first ferroic property was an unconventional magnetism: The electrons coordinated their orbital motion, like planets circling in the same direction. (In conventional magnets, electrons coordinate their “spin” — rotating in the same direction, while staying relatively fixed in space.)

The second ferroic property had to do with graphene’s electronic “valley.” In every conductive material, there are certain energy levels that electrons can occupy. A valley represents the lowest energy state that an electron can naturally settle. As it turns out, there are two possible valleys in graphene. Normally, electrons have no preference for either valley and settle equally into both.

But in five-layer graphene, the team found that the electrons began to coordinate, and preferred to settle in one valley over the other. This second coordinated behavior indicated a ferroic property that, combined with the electrons’ unconventional magnetism, gave the structure a rare, multiferroic state.

“We knew something interesting would happen in this structure, but we didn’t know exactly what, until we tested it,” says co-first author Lu, a postdoc in Ju’s group. “It’s the first time we’ve seen a ferro-valleytronics, and also the first time we’ve seen a coexistence of ferro-valleytronics with unconventional ferro-magnet.”

The team showed they could control both ferroic properties using an electric field. They envision that, if engineers can incorporate five-layer graphene or similar multiferroic materials into a memory chip, they could, in principle, use the same, low-power electric field to manipulate the material’s electrons in two ways rather than one, and effectively double the data that could be stored on a chip compared to conventional multiferroics. While that vision is far from practical realization, the team’s results break new ground in the search for better, more efficient electronic, magnetic and valleytronic devices.

This research was done, in part, using the electron-beam lithography facility run by MIT.nano, and is funded, in part, by the National Science Foundation and the Sloan Foundation.

MIT physicists have metaphorically turned graphite, or pencil lead, into gold by isolating five ultrathin flakes stacked in a specific order. The resulting material can then be tuned to exhibit three important properties never before seen in natural graphite.

“It is kind of like one-stop shopping,” says Long Ju, an assistant professor in the Department of Physics and leader of the work, which is reported in the Oct. 5 issue of Nature Nanotechnology. “Nature has plenty of surprises. In this case, we never realized that all of these interesting things are embedded in graphite.”

Further, he says, “It is very rare material to find materials that can host this many properties.”

Graphite is composed of graphene, which is a single layer of carbon atoms arranged in hexagons resembling a honeycomb structure. Graphene, in turn, has been the focus of intense research since it was first isolated about 20 years ago. More recently, about five years ago, researchers including a team at MIT discovered that stacking individual sheets of graphene, and twisting them at a slight angle to each other, can impart new properties to the material, from superconductivity to magnetism. The field of “twistronics” was born.

In the current work, “we discovered interesting properties with no twisting at all,” says Ju, who is also affiliated with the Materials Research Laboratory.

He and colleagues discovered that five layers of graphene arranged in a certain order allow the electrons moving around inside the material to talk with each other. That phenomenon, known as electron correlation, “is the magic that makes all of these new properties possible,” Ju says.

Bulk graphite — and even single sheets of graphene — are good electrical conductors, but that’s it. The material Ju and colleagues isolated, which they call pentalayer rhombohedral stacked graphene, becomes much more than the sum of its parts.

Novel microscope

Key to isolating the material was a novel microscope Ju built at MIT in 2021 that can quickly and relatively inexpensively determine a variety of important characteristics of a material at the nanoscale. Pentalayer rhombohedral stacked graphene is only a few billionths of a meter thick.

Scientists including Ju were looking for multilayer graphene that was stacked in a very precise order, known as rhombohedral stacking. Says Ju, “there are more than 10 possible stacking orders when you go to five layers. Rhombohedral is just one of them.” The microscope Ju built, known as Scattering-type Scanning Nearfield Optical Microscopy, or s-SNOM, allowed the scientists to identify and isolate only the pentalayers in the rhombohedral stacking order they were interested in.

Three in one

From there, the team attached electrodes to a tiny sandwich composed of boron nitride “bread” that protects the delicate “meat” of pentalayer rhombohedral stacked graphene. The electrodes allowed them to tune the system with different voltages, or amounts of electricity. The result: They discovered the emergence of three different phenomena depending on the number of electrons flooding the system.

“We found that the material could be insulating, magnetic, or topological,” Ju says. The latter is somewhat related to both conductors and insulators. Essentially, Ju explains, a topological material allows the unimpeded movement of electrons around the edges of a material, but not through the middle. The electrons are traveling in one direction along a “highway” at the edge of the material separated by a median that makes up the center of the material. So the edge of a topological material is a perfect conductor, while the center is an insulator.

“Our work establishes rhombohedral stacked multilayer graphene as a highly tunable platform to study these new possibilities of strongly correlated and topological physics,” Ju and his coauthors conclude in Nature Nanotechnology.

In addition to Ju, authors of the paper are Tonghang Han and Zhengguang Lu. Han is a graduate student in the Department of Physics; Lu is a postdoc in the Materials Research Laboratory. The two are co-first authors of the paper.

Other authors are Giovanni Scuri, Jiho Sung, Jue Wang and Hongkun Park of Harvard University; Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan; and Tianyi Han of the MIT Department of Physics.

This work was supported by a Sloan Fellowship; the U.S. National Science Foundation; the U.S. Office of the Under Secretary of Defense for Research and Engineering; the Japan Society for the Promotion of Science KAKENHI;  the World Premier International Research Initiative of Japan; and the U.S. Air Force Office of Scientific Research.

Ordinary pencil lead holds extraordinary properties when shaved down to layers as thin as an atom. A single, atom-thin sheet of graphite, known as graphene, is just a tiny fraction of the width of a human hair. Under a microscope, the material resembles a chicken-wire of carbon atoms linked in a hexagonal lattice.

Despite its waif-like proportions, scientists have found over the years that graphene is exceptionally strong. And when the material is stacked and twisted in specific contortions, it can take on surprising electronic behavior.

Now, MIT physicists have discovered another surprising property in graphene: When stacked in five layers, in a rhombohedral pattern, graphene takes on a very rare, “multiferroic” state, in which the material exhibits both unconventional magnetism and an exotic type of electronic behavior, which the team has coined ferro-valleytricity.

“Graphene is a fascinating material,” says team leader Long Ju, assistant professor of physics at MIT. “Every layer you add gives you essentially a new material. And now this is the first time we see ferro-valleytricity, and unconventional magnetism, in five layers of graphene. But we don’t see this property in one, two, three, or four layers.”

The discovery could help engineers design ultra-low-power, high-capacity data storage devices for classical and quantum computers.

“Having multiferroic properties in one material means that, if it could save energy and time to write a magnetic hard drive, you could also store double the amount of information compared to conventional devices,” Ju says.

His team reports their discovery today in Nature. MIT co-authors include lead author Tonghang Han, plus Zhengguang Lu, Tianyi Han, and Liang Fu; along with Harvard University collaborators Giovanni Scuri, Jiho Sung, Jue Wang, and Hongkun Park; and Kenji Watanabe and Takashi Taniguchi of the National Institute for Materials Science in Japan.

A preference for order

A ferroic material is one that displays some coordinated behavior in its electric, magnetic, or structural properties. A magnet is a common example of a ferroic material: Its electrons can coordinate to spin in the same direction without an external magnetic field. As a result, the magnet points to a preferred direction in space, spontaneously.

Other materials can be ferroic through different means. But only a handful have been found to be multiferroic — a rare state in which multiple properties can coordinate to exhibit multiple preferred states. In conventional multiferroics, it would be as if, in addition to the magnet pointing toward one direction, the electric charge also shifts in a direction that is independent from the magnetic direction.  

Multiferroic materials are of interest for electronics because they could potentially increase the speed and lower the energy cost of hard drives. Magnetic hard drives store data in the form of magnetic domains — essentially, microscopic magnets that are read as either a 1 or a 0, depending on their magnetic orientation. The magnets are switched by an electric current, which consumes a lot of energy and cannot operate quickly. If a storage device could be made with multiferroic materials, the domains could be switched by a faster, much lower-power electric field. Ju and his colleagues were curious about whether multiferroic behavior would emerge in graphene. The material’s extremely thin structure is a unique environment in which researchers have discovered otherwise hidden, quantum interactions. In particular, Ju wondered whether graphene would display multiferroic, coordinated behavior among its electrons when arranged under certain conditions and configurations.

“We are looking for environments where electrons are slowed down — where their interactions with the surrounding lattice of atoms is small, so that their interactions with other electrons can come through,” Ju explains. “That’s when we have some chance of seeing interesting collective behaviors of electrons.”

The team carried out some simple calculations and found that some coordinated behavior among electrons should emerge in a structure of five graphene layers stacked together in a rhombohedral pattern. (Think of five chicken-wire fences, stacked and slightly shifted such that, viewed from the top, the structure would resemble a pattern of diamonds.)

“In five layers, electrons happen to be in a lattice environment where they move very slowly, so they can interact with other electrons effectively,” Ju says. “That’s when electron correlation effects start to dominate, and they can start to coordinate into certain preferred, ferroic orders.”

Magic flakes

The researchers then went into the lab to see whether they could actually observe multiferroic behavior in five-layer graphene. In their experiments, they started with a small block of graphite, from which they carefully exfoliated individual flakes. They used optical techniques to examine each flake, looking specifically for five-layer flakes, arranged naturally in a rhombohedral pattern.

“To some extent, nature does the magic,” said lead author and graduate student Han. “And we can look at all these flakes and tell which has five layers, in this rhombohedral stacking, which is what should give you this slowing-down effect in electrons.”

The team isolated several five-layer flakes and studied them at temperatures just above absolute zero. In such ultracold conditions, all other effects, such as thermally induced disorders within graphene, should be dampened, allowing interactions between electrons, to emerge. The researchers measured electrons’ response to an electric field and a magnetic field, and found that indeed, two ferroic orders, or sets of coordinated behaviors, emerged.

The first ferroic property was an unconventional magnetism: The electrons coordinated their orbital motion, like planets circling in the same direction. (In conventional magnets, electrons coordinate their “spin” — rotating in the same direction, while staying relatively fixed in space.)

The second ferroic property had to do with graphene’s electronic “valley.” In every conductive material, there are certain energy levels that electrons can occupy. A valley represents the lowest energy state that an electron can naturally settle. As it turns out, there are two possible valleys in graphene. Normally, electrons have no preference for either valley and settle equally into both.

But in five-layer graphene, the team found that the electrons began to coordinate, and preferred to settle in one valley over the other. This second coordinated behavior indicated a ferroic property that, combined with the electrons’ unconventional magnetism, gave the structure a rare, multiferroic state.

“We knew something interesting would happen in this structure, but we didn’t know exactly what, until we tested it,” says co-first author Lu, a postdoc in Ju’s group. “It’s the first time we’ve seen a ferro-valleytronics, and also the first time we’ve seen a coexistence of ferro-valleytronics with unconventional ferro-magnet.”

The team showed they could control both ferroic properties using an electric field. They envision that, if engineers can incorporate five-layer graphene or similar multiferroic materials into a memory chip, they could, in principle, use the same, low-power electric field to manipulate the material’s electrons in two ways rather than one, and effectively double the data that could be stored on a chip compared to conventional multiferroics. While that vision is far from practical realization, the team’s results break new ground in the search for better, more efficient electronic, magnetic and valleytronic devices.

This research was done, in part, using the electron-beam lithography facility run by MIT.nano, and is funded, in part, by the National Science Foundation and the Sloan Foundation.